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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Raupp-Pereira, F.
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (18/18 displayed)
- 2019Characterization of pulp and paper mill waste for the production of waste-based cementcitations
- 2018Wastes from pulp and paper mills - A review of generation and recycling alternativescitations
- 2018Structural Refinement by the Rietveld Method on Clinkers Obtained from Waste from Pulp and Paper Millscitations
- 2018Thermal characterization of hydrated eco-friendly clinkers produced from pulp and paper mill wastecitations
- 2017Waste-containing clinkers: Valorization of alternative mineral sources from pulp and paper millscitations
- 2016Life cycle assessment of the production of cement: A Brazilian case studycitations
- 2014The influence of porogene additives on the properties of mortars used to control the ambient moisturecitations
- 2014Development of porogene-containing mortars for levelling the indoor ambient moisturecitations
- 2008Al-27 and Si-29 NMR and XRD characterisation of clinkers: standard phases and new waste based formulationscitations
- 2008New waste based clinkers: Belite and lime formulationscitations
- 2007Effects of potable water filtration sludge on the rheological behaviour of one-coat plastering mortarscitations
- 2007Setting behaviour of waste-based cements estimated by impedance spectroscopy and temperature measurements
- 2006Light aggregates from industrial wastes | Aggregati leggeri da rifiuti industriali
- 2006Ceramic formulations prepared with industrial wastes and natural sub-productscitations
- 2005Lightweight aggregates based on industrial wastes
- 2005Cement formulations made of different wastes and natural sub-probucts
- 2005Refractory mortars based on industrial wastes
- 2005Lightweight expanded clays based on industrial wastes
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article
New waste based clinkers: Belite and lime formulations
Abstract
This work describes the formulation of new belite-based (CR2) and lime-based (CR3) cementitious materials derived from industrial wastes, such as sludges (generated in the Al-anodising and surface coating industrial processes, potable water filtration/cleaning operations and in marble sawing processes) and foundry sand.Powder mixtures were prepared and fired at different temperatures. For comparison, similar formulations were prepared with pre-treated and commercially available natural raw materials and processed in similar conditions. The thermal process was followed by differential scanning calorimetry (DSC) and high-temperature powder X-ray diffraction (HT-XRD) studies.The CR2 clinker was found to contain belite as the main cementitious phase, the main polymorph being identified by NMR. The CR3 clinker contained common cementitious phases, such as C3A and C3S, but free lime and calcium aluminium oxide sulphates were also identified by high temperature XRD and NMR.Then the corresponding cement was prepared and the evolution of the mechanical strength with time was evaluated. The lime-based cement obtained from wastes shows a stronger hardening character than the standard material, which tends to show dusting phenomena due to the presence of a reasonable amount of free lime (as the result of its expansive reaction with ambient moisture). Some fluxing impurities (e.g. alkalis) present in the waste materials improve the overall reactivity of the mixture and induces the combination of the lime in CR3. Raman, XPS and FIB techniques were used to fully characterise the aged cements.