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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Ghouri, Zafar Khan
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (20/20 displayed)
- 2022Cooperative electrocatalytic effect of Pd and Ce alloys nanoparticles in PdCe@CNWs electrode for oxygen evolution reaction (OER)citations
- 2022Incorporation of manganese carbonyl sulfide ((Mn2S2 (CO)7) and mixed metal oxides-decorated reduced graphene oxide (MnFeCoO4/rGO) as a selective anode toward efficient OER from seawater splitting under neutral pH conditionscitations
- 2021Early transition-metal-based binary oxide/nitride for efficient electrocatalytic hydrogen evolution from saline water in different pH environmentscitations
- 2021Incorporation of Manganese Carbonyl Sulfide ((Mn2S2 (CO)7) and Mixed Metal Oxides-Decorated Reduced Graphene Oxide (MnFeCoO4/rGO) as a Selective Anode Toward Efficient OER from Seawater Splitting Under Neutral PH Conditions
- 2021Synthesis and experimental investigation of δ-MnO2/N-rGO nanocomposite for Li-O2 batteries applicationscitations
- 2021Theoretical and experimental investigations of Co-Cu bimetallic alloys-incorporated carbon nanowires as an efficient bi-functional electrocatalyst for water splittingcitations
- 2019Engineering of nickel based catalyst for direct urea fuel cell-energy from municipal liquid waste (Mlw)
- 2018Application of FTIR and LA-ICPMS spectroscopies as a possible approach for biochemical analyses of different rat brain regionscitations
- 2018Stable N-doped & FeNi-decorated graphene non-precious electrocatalyst for Oxygen Reduction Reaction in Acid Mediumcitations
- 2018Surfactant/organic solvent free single-step engineering of hybrid graphene-Pt/TiO2 nanostructure: Efficient photocatalytic system for the treatment of wastewater coming from textile industriescitations
- 2017Engineering of magnetically separable ZnFe2O4@ TiO2 nanofibers for dye-sensitized solar cells and removal of pollutant from watercitations
- 2016Photoluminescent and transparent Nylon-6 nanofiber mat composited by CdSe@ZnS quantum dots and poly (methyl methacrylate)citations
- 2016Nano-designed λ-CaCO3@rGO photo-catalyst for effective adsorption and simultaneous removal of organic pollutantcitations
- 2016Nickel nanoparticles-decorated graphene as highly effective and stable electrocatalyst for urea electrooxidationcitations
- 2016Supercapacitors based on ternary nanocomposite of TiO2&Pt@graphenescitations
- 2016Nano-engineered ZnO/CeO2 dots@CNFs for fuel cell applicationcitations
- 2015Synthesis and Electrochemical Properties of MnO 2 and Co-Decorated Graphene as Novel Nanocomposite for Electrochemical Super Capacitors Applicationcitations
- 2015Synthesis and characterization of Nitrogen-doped &CaCO3-decorated reduced graphene oxide nanocomposite for electrochemical supercapacitorscitations
- 2015Effective photocatalytic efficacy of hydrothermally synthesized silver phosphate decorated titanium dioxide nanocomposite fiberscitations
- 2014Co/CeO2-decorated carbon nanofibers as effective non-precious electro-catalyst for fuel cells application in alkaline mediumcitations
Places of action
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article
Synthesis and experimental investigation of δ-MnO2/N-rGO nanocomposite for Li-O2 batteries applications
Abstract
<p>Among all the electrocatalysts for Lithium-Air battery (Li-air), Platinum Pt is the best performing cathode material. However, the high cost of noble Pt metal and scarcity nature impedes the use of Pt-based catalysts from being extensivity used in commercial applications. Therefore, there is an urgent need to develop an efficient and cost-effective alternate electrocatalyst to replace Pt-based materials in lithium-oxygen (Li-O<sub>2</sub>) battaries. In the present work, δ-MnO<sub>2</sub>/N-rGO composite (MNGC) has been synthesized by a simple non-template hydrothermal approach. MNGC with a porous wall structure composed of ultrathin nanosheets exhibits excellent electrochemical properties for oxidation–reduction reaction (ORR). MNGC can provide numerous pathways for abundant oxygen and electrolyte access to facilitate the mass transfer of lithium-ion. Such a well-designed structure offers the right electrocatalyst for the air cathode in lithium-oxygen (Li-O<sub>2</sub>) battaries. The prepared samples principal characteristics are analyzed, which verified the successful synthesis of sheet-like δ-MnO<sub>2</sub> grown over the surface of nitrogen-doped reduced graphene oxide (N-rGO). Linear sweep voltammetry (LSV) results of MNGC showed enhanced ORR performance compared to MnO<sub>2</sub> and N-rGO in terms of the half-wave potential, limiting current, and onset potential. MNGC electrode displayed superior cyclic performances of Li-air with a stable specific capacity, decreased overpotential, reversibility, and rate capability. Li-O<sub>2</sub> battery was also tested with MNGN electrode for limited discharge capacity of 500 mAh/g, long-term cycling was achieved without electrolyte degradation. A high specific capacity of 5250 mAh/g was obtained at a high current density of 0.2 mA/cm<sup>2</sup>.</p>