| People | Locations | Statistics |
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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Bordbar-Khiabani, Aydin
Aalto University
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (8/8 displayed)
- 2024Improving the inflammatory-associated corrosion behavior of magnesium alloys by Mn3O4 incorporated plasma electrolytic oxidation coatingscitations
- 2024Improving the inflammatory-associated corrosion behavior of magnesium alloys by Mn3O4 incorporated plasma electrolytic oxidation coatingscitations
- 2024Corrosion behavior of PEO coatings with Mn3O4 on Mg-Zn-Ca alloys in inflammatory conditions
- 2024Tuning biomechanical behavior and biocompatibility of Mg–Zn–Ca alloys by Mn3O4 incorporated plasma electrolytic oxidation coatingscitations
- 2024Evaluation of in vitro degradation and associated risks of novel biomaterials for implants ; Uusien implanttibiomateriaalien in vitro-hajoamisen ja siihen liittyvien riskien evaluointicitations
- 2023Electrochemical and biological characterization of Ti–Nb–Zr–Si alloy for orthopedic applicationscitations
- 2023Octacalcium Phosphate-Laden Hydrogels on 3D-Printed Titanium Biomaterials Improve Corrosion Resistance in Simulated Biological Mediacitations
- 2023Electrochemical behavior of additively manufactured patterned titanium alloys under simulated normal, inflammatory, and severe inflammatory conditionscitations
Places of action
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article
Improving the inflammatory-associated corrosion behavior of magnesium alloys by Mn3O4 incorporated plasma electrolytic oxidation coatings
Abstract
<p>Biodegradable magnesium alloys for orthopedic bone fixation have been introduced for various fields of application. The corrosion resistance of magnesium implants weakens in physicochemical environments and is further compromised during post-implantation inflammation. In this study, Mn<sub>3</sub>O<sub>4</sub>-incorporated plasma electrolyte oxidation (PEO) coatings were developed on Mg-Zn-Ca substrate through two approaches: the addition of KMnO<sub>4</sub> salt and the inclusion of Mn<sub>3</sub>O<sub>4</sub> nanoparticles into the electrolyte composition. Incorporating additives into electrolytes led to a reduction in surface porosity and an increase in coating thickness in both synthesis approaches. The electrochemical and immersion corrosion tests were conducted under simulated normal conditions and inflammatory conditions, where inflammatory solutions were prepared with the addition of hydrogen peroxide (H<sub>2</sub>O<sub>2</sub>) and hydrochloric (HCl) acid. Both corrosion studies revealed that inflammation significantly increased the corrosion rate of the uncoated Mg-Zn-Ca biomaterial, escalating from approximately 2 mm·y<sup>-1</sup> to 16 mm·y<sup>-1</sup>. Moreover, corrosion studies showed that the composite PEO coatings, incorporating Mn<sub>3</sub>O<sub>4</sub> nanoparticles (MnPR-PEO), demonstrated superior corrosion performance among all coated samples. Potentiodynamic polarization results indicated a substantial reduction in corrosion current density, decreasing from 73.9 μA·cm<sup>-</sup> <sup>2</sup> for basic PEO coatings to 5.5 μA·cm<sup>-</sup> <sup>2</sup> for MnPR-PEO coatings. The improved performance of Mn<sub>3</sub>O<sub>4</sub>-incorporated PEO coatings, attributed to their catalytic H<sub>2</sub>O<sub>2</sub> scavenging, suggests promise for magnesium implants, offering enhanced corrosion resistance and potential biomedical application benefits.</p>