| People | Locations | Statistics |
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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Levenfeld, Belen
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (5/5 displayed)
- 2024Advancements in Quasi-Solid-State Li Batteries: A Rigid Hybrid Electrolyte Using LATP Porous Ceramic Membrane and Infiltrated Ionic Liquid
- 2023Using Metal-Organic Framework HKUST-1 for the Preparation of High-Conductive Hybrid Membranes Based on Multiblock Copolymers for Fuel Cellscitations
- 2023All-solid-state sodium-ion batteries operating at room temperature based on NASICON-type NaTi2(PO4)3 cathode and ceramic NASICON solid electrolytecitations
- 2023All-solid-state sodium-ion batteries operating at room temperature based on NASICON-type NaTi 2 (PO 4 ) 3 cathode and ceramic NASICON solid electrolyte:A complete in situ synchrotron X-ray studycitations
- 2018Additive-free Li<sub>4</sub>Ti<sub>5</sub>O<sub>12</sub> thick electrodes for Li-ion batteries with high electrochemical performancecitations
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article
All-solid-state sodium-ion batteries operating at room temperature based on NASICON-type NaTi2(PO4)3 cathode and ceramic NASICON solid electrolyte
Abstract
<p>All-solid-state sodium-ion batteries that work at ambient temperature are a potential approach for large-scale energy storage systems. Nowadays, ceramic solid electrolytes are gaining attention because of their good ionic conductivity and excellent mechanical and chemical stabilities. Furthermore, a good interface between electrode and solid electrolyte is also required to achieve successful cell performances. In this work, sintered ceramic layer electrolyte Na<sub>3.16</sub>Zr<sub>1.84</sub>Y<sub>0.16</sub>Si<sub>2</sub>PO<sub>12</sub>, with high ionic conductivity (0.202 mS/cm at room temperature), are prepared by using uniaxial pressing followed by a sintering process. The conductive carbon coated NASICON material (NaTi<sub>2</sub>(PO<sub>4</sub>)<sub>3</sub>/C) exhibits, as cathode material, enhanced rate capability and stability for sodium ion batteries for high carbon (18.95 %) coated sample. At C/10, the optimized cathode (with higher carbon content) achieves a remarkable initial discharge capacity of 107.3 mAh/g (reversible capacity of 101.4 mAh/g), a sufficient rate capability up to a rate of 10C, and a long cycle life (capacity retention of 58% after 950 cycles). The one-stage reversible biphasic reaction mechanism and potential-dependent structure–property of NaTi<sub>2</sub>(PO<sub>4</sub>)<sub>3</sub> can be explained by employing in situ X-ray synchrotron method. Sequential Rietveld refinements of the in situ data show the evolution of the Na-poor NaTi<sub>2</sub>(PO<sub>4</sub>)<sub>3</sub> and Na-rich Na<sub>3</sub>Ti<sub>2</sub>(PO<sub>4</sub>)<sub>3</sub> phase fractions (wt%), unit cell characteristics, and unit cell volume. The design of an all-solid-state sodium ion half-cell with a NaTi<sub>2</sub>(PO<sub>4</sub>)<sub>3</sub>/C cathode and a Na<sub>3.16</sub>Zr<sub>1.84</sub>Y<sub>0.16</sub>Si<sub>2</sub>PO<sub>12</sub> solid-state electrolyte interface results in stable capacity of 83.6 mAh/g at C/10 and excellent reversible capacity at high C-rate. The results show that sintered NASICON-based electrolytes can significantly contribute for the fabrication of all-solid-state sodium-ion battery due to the superior conductivity and stability.</p>