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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Ansari, Mohd Zahid
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (10/10 displayed)
- 2024Numerical crashworthiness analysis of 2014 Aluminium- Silicon Carbide Particle (SiCp) foam filled Carbon Fiber-Reinforced Plastic (CFRP) tube under impact loading
- 2024Designing of high performance MoS<sub>2</sub>@VZnS//AC hybrid battery supercapacitor device for the electrochemical energy storage and glucose detectioncitations
- 2023Structural study of atomically precise doped Au38-xAgx NCs@ ZIF-8 electrode material for energy storage applicationcitations
- 2023Hole-Transport Material Engineering in Highly Durable Carbon-Based Perovskite Photovoltaic Devicescitations
- 2023Preparation of wafer-scale highly conformalamorphous hafnium dioxide thin films by atomic layer deposition using a thermally stable boratabenzene ligand-containing hafnium precursor ; Příprava vysoce konformních tenkých filmů amorfního oxidu hafničitého pomocí depozice atomární vrstvev za použití tepelně stabilního prekurzoru hafnia obsahujícího boratabenzenový ligand pokrývajících velké plochycitations
- 2023In Situ Grown Heterostructure Based on MOF-Derived Carbon Containing n-Type Zn-In-S and Dry-Oxidative p-Type CuO as Pseudocapacitive Electrode Materialscitations
- 2023Understanding the Diffusion-Dominated Properties of MOF-Derived Ni–Co–Se/C on CuO Scaffold Electrode using Experimental and First Principle Studycitations
- 2022Factors affecting the growth formation of nanostructures and their impact on electrode materialscitations
- 2022Effect of growth duration of Zn0.76Co0.24S interconnected nanosheets for high-performance flexible energy storage electrode materialscitations
- 2021Low-temperature growth of crystalline Tin(II) monosulfide thin films by atomic layer deposition using a liquid divalent tin precursor ; Nízkoteplotní růst tenkých vrstev krystalického monosulfidu cínatého pomocí depozice atomových vrstev s využitím kapalného prekurzoru dvojmocného cínucitations
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article
Structural study of atomically precise doped Au38-xAgx NCs@ ZIF-8 electrode material for energy storage application
Abstract
Fast-charging storage devices have attained attention in recent years due to their prospective wide range of applications in microelectronic gadgets and hybrid electric vehicles. In the pursuit of new efficient high-capacity electrodes, the implication of atomically precise metal nanoclusters (NCs) in the field of supercapacitors is rare. Herein, structurally distorted atomically precise doped Au<sub>38-<i>x</i></sub>Ag<sub><i>x</i></sub> NCs protected by 2,4-dimethylbenzenethiolate (2,4-DMBT) were synthesized by doping Ag atoms to the parent monometallic Au38 NCs. A general strategy to integrate structurally distorted atomically precise doped Au<sub>38-<i>x</i></sub>Ag<sub><i>x</i></sub> NCs with ZIF-8 (Au<sub>38-<i>x</i></sub>Ag<sub><i>x</i></sub> NCs@ZIF-8) was employed for methodical electrochemical and physicochemical studies of intrinsic energy storage mechanisms. The structural changes of doped Au<sub>38-<i>x</i></sub>Ag<sub><i>x</i></sub> NCs@ZIF-8 were systematically revealed and the effect of heteroatom doping, synergistic effect, reduced HOMO-LUMO gap (HLG) of highly distorted doped Au<sub>38-<i>x</i></sub>Ag<sub><i>x</i></sub> NCs@ZIF-8 resulted in enhanced electronic transfer kinetics, ultimately improving specific capacitance 2.2 times higher than the parent monometallic Au38 NCs. Doped Au<sub>38-<i>x</i></sub>Ag<sub><i>x</i></sub> NCs@ZIF-8 based hybrid supercapacitor (HSC) provides a high energy density of 14.75 Wh kg<sup>−1</sup> and power density of 2212.8 W kg<sup>−1</sup> . The development of structurally distorted atomically precise doped Au<sub>38-<i>x</i></sub>Ag<sub><i>x</i></sub> NCs@ZIF-8 electrode material can pave the ways for doped metal nanoclusters for next-generation energy storage devices.<br/><br/>© 2023 Elsevier B.V.<br/>