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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Hélix-Nielsen, Claus
Technical University of Denmark
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (14/14 displayed)
- 2023Facile Fabrication of Flexible Ceramic Nanofibrous Membranes for Enzyme Immobilization and Transformation of Emerging Pollutantscitations
- 2023Facile Fabrication of Flexible Ceramic Nanofibrous Membranes for Enzyme Immobilization and Transformation of Emerging Pollutantscitations
- 2023Synthesis of magnetic nanoparticles with covalently bonded polyacrylic acid for use as forward osmosis draw agentscitations
- 2022Concentrating hexavalent chromium electroplating wastewater for recovery and reuse by forward osmosis using underground brine as draw solutioncitations
- 2021Employing the synergistic effect between aquaporin nanostructures and graphene oxide for enhanced separation performance of thin-film nanocomposite forward osmosis membranescitations
- 2021Impedance characterization of biocompatible hydrogel suitable for biomimetic lipid membrane applicationscitations
- 2021Impact of sodium hypochlorite on rejection of non-steroidal anti-inflammatory drugs by biomimetic forward osmosis membranescitations
- 2019Synthesis of Poly-Sodium-Acrylate (PSA)-Coated Magnetic Nanoparticles for Use in Forward Osmosis Draw Solutionscitations
- 2016Influence of feed composition and membrane fouling on forward osmosis performance
- 2015A reusable device for electrochemical applications of hydrogel supported black lipid membranescitations
- 2015A feasibility study of ultrafiltration/reverse osmosis (UF/RO)-based wastewater treatment and reuse in the metal finishing industrycitations
- 2012Tailoring Properties of Biocompatible PEG-DMA Hydrogels with UV Lightcitations
- 2011Surface Modifications of Support Partitions for Stabilizing Biomimetic Membrane Arrayscitations
- 2011Electrochemical characterization of hydrogels for biomimetic applicationscitations
Places of action
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article
Facile Fabrication of Flexible Ceramic Nanofibrous Membranes for Enzyme Immobilization and Transformation of Emerging Pollutants
Abstract
Biocatalytic nanofibrous membranes, integrating the benefits of membranes and enzymes, have drawn attention in wastewater treatment because of their efficient catalytic performance and operational catalytic stability. However, these membranes are typically polymeric membranes, and their fate as plastic waste is not considered environmentally sustainable. By contrast, ceramic-based membranes are considered more environmental-friendly due to their low-risk recycling and disposal procedures, but the brittleness of these membranes limits their implementation. Here, we report the fabrication of high flexibility SiO<sub>2</sub> biocatalytic nanofiber membranes (NFMs) and their previously unreported application in emerging pollutant bioremediation. We used a commercial laccase (EC 1.10.3.2) as a model biocatalyst to evaluate the impact of different strategies to improve the catalytic properties of the NFMs in terms of enzyme load and apparent activity per membrane weight. Enzyme immobilization with the co-deposition of polydopamine (PDA) and polyethyleneimine (PEI) resulted in the best immobilization yield (57.9 ± 0.5 %) and apparent activity of 6.4 ± 1.1 U g<sup>−1</sup> membrane. Compared to the free enzyme, the fabricated bio-catalytic membranes maintained 80 % of residual activity after five cycles. In addition, the membranes exhibited > 95 % depletion of the five emerging pollutants diclofenac, mefenamic acid, benzefabrite, bicalutamide, and clarithromycin. The successful fabrication of flexible biocatalytic ceramic membranes holds promise as a new technological platform for sustainable wastewater treatment and brings novel insights into a previously less explored realm of membrane applications.