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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Gomez-Romero, Pedro
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (15/15 displayed)
- 2018Unveiling BiVO4 nanorods as a novel anode material for high performance lithium ion capacitors: beyond intercalation strategiescitations
- 2018Energy harvesting from neutralization reactions with saline feedbackcitations
- 2018Hybrid graphene-polyoxometalates nanofluids as liquid electrodes for dual energy storage in novel flow cellscitations
- 2018Ultrathin hierarchical porous carbon nanosheets for high-performance supercapacitors and redox electrolyte energy storagecitations
- 2017Mimics of microstructures of Ni substituted Mn1-xNixCo2O4 for high energy density asymmetric capacitorscitations
- 2017Ultrahigh energy density supercapacitors through a double hybrid strategycitations
- 2017Nanostructured mixed transition metal oxides for high performance asymmetric supercapacitors: Facile synthetic strategycitations
- 2017Fundamentals of binary metal oxide-based supercapacitorscitations
- 2017Capacitive vs faradaic energy storage in a hybrid cell with LiFePO4/RGO positive electrode and nanocarbon negative electrodecitations
- 2016Aqueous synthesis of LiFePO4 with Fractal Granularitycitations
- 2016Electrochemical supercapacitive properties of polypyrrole thin films: influence of the electropolymerization methodscitations
- 2015Asymmetric supercapacitors based on hybrid CuO@Reduced Graphene Oxide@Sponge versus Reduced Graphene Oxide@Sponge Electrodescitations
- 2015An innovative 3-D nanoforest heterostructure made of polypyrrole coated silicon nanotrees for new high performance hybrid micro-supercapacitorscitations
- 2015Low-cost flexible supercapacitors with high-energy density based on nanostructured MnO2 and Fe2O3 thin films directly fabricated onto stainless steelcitations
- 2015A high voltage solid state symmetric supercapacitor based on graphene-polyoxometalate hybrid electrodes with a hydroquinone doped hybrid gel-electrolytecitations
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article
Mimics of microstructures of Ni substituted Mn1-xNixCo2O4 for high energy density asymmetric capacitors
Abstract
The preparation of nanostructured hierarchical Mn<sub>1−x</sub>Ni<sub>x</sub>Co<sub>2</sub>O<sub>4</sub> metal oxides as efficient supercapacitors of different structures and configurations especially for the miniaturized electronics is still a challenge. In this context, we report template free facile hydrothermal synthesis of hierarchical nanostructured Mn<sub>1−x</sub>Ni<sub>x</sub>Co<sub>2</sub>O<sub>4</sub> with excellent supercapacitive performance. Significantly, the morphology of pure MnCo<sub>2</sub>O<sub>4</sub> transformed from 3D microcubes to 1D nanowires with incorporation of Ni. The electrochemical study shows highest specific capacitance i.e. 1762 F/g for Mn<sub>0.4</sub>Ni<sub>0.6</sub>Co<sub>2</sub>O<sub>4</sub> with high cycling stability of 89.2% which is much higher than pristine MnCo<sub>2</sub>O<sub>4</sub> and NiCo<sub>2</sub>O<sub>4</sub>. Later, asymmetric capacitor has been fabricated successfully using Mn<sub>0.4</sub>Ni<sub>0.6</sub>Co<sub>2</sub>O<sub>4</sub> nanowires as positive electrode and activated carbon (AC) as negative electrode in a KOH aqueous electrolyte. An asymmetric cell could be cycled reversibly in the high-voltage range of 0–1.5 V and displays intriguing performances with a specific capacitance of 112.8 F/g (6.87 F/cm<sup>3</sup>) and high energy density of 35.2 Wh/kg (2.1 mWh/cm<sup>3</sup>). Importantly, this asymmetric capacitor device exhibits an excellent long cycle life along with 83.2% specific capacitance retained after 2000 cycles.