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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Cussen, Edmund
Technological University Dublin
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (17/17 displayed)
- 2017Insulating to metallic behaviour in the cation ordered perovskites Ba2Nd1−xFexMoO6citations
- 2016Microwave-assisted syntheis of highly crystalline, multifunctional iron oxide nanocomposites for imaging applicationscitations
- 2016Scalable continuous solvothermal synthesis of metal organic framework (MOF-5) crystalscitations
- 2015Structural and magnetic study of Yb3+ in the perovskites Sr2YbMO6 (M = Nb, Ta, Sb)citations
- 2014Structural and magnetic study of order−disorder behavior in the double perovskites Ba2Nd1−xMnxMoO6citations
- 2013Effect of synthesis conditions on formation pathways of metal organic framework (MOF-5) Crystalscitations
- 2013A neutron diffraction study of structural distortion and magnetic ordering in the cation-ordered perovskites Ba2Nd1−xYxMoO6citations
- 2010Spontaneous formation of crystalline lithium molybdate from solid reagents at room temperaturecitations
- 2010Lithium Ion conduction in oxidescitations
- 2008The structure of the lithium-rich garnets li6la2m2o12 and li6.4sr1.4la1.6m2o12 (m = sb, ta)citations
- 2008Switching on fast lithium ion conductivity in garnetscitations
- 2007Structural and magnetic study of the cation-ordered perovskites Ba2−xSrxErMoO6citations
- 2006Magnetic order arising from structural distortion: the structure and magnetic properties of Ba2LnMoO6citations
- 2005The first layered analogue of Sr2FeMoO6; the structure and electronic properties of Sr4FeMoO8citations
- 2004Adsorption of gases and vapors on nanoporous Ni-2(4,4 '-bipyridine)(3)(NO3)(4) metal-organic framework materials templated with methanol and ethanol: Structural effects in adsorption kineticscitations
- 2002Flexible sorption and transformation behavior in a microporous metal-organic frameworkcitations
- 2001Adsorption dynamics of gases and vapors on the nanoporous metal organic framework material Ni-2(4,4 '-bipyridine)(3)(NO3)(4): guest modification of host sorption behaviorcitations
Places of action
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article
Scalable continuous solvothermal synthesis of metal organic framework (MOF-5) crystals
Abstract
Metal-organic frameworks (MOF)s are well suited as nanoporous materials for applications such as gas storage, catalysis and in medical devices. Literature predominantly covers information on the batch synthesis of MOF-5, however, for an industrially viable product to be formed, bridging the gap to scalable continuous processing is essential. Here, we show that crystals of MOF-5 can be formed in a scalable solvothermal continuous process with a maximum space time yield of nearly 1000 kg m-3 day-1. Analysis of the solid output as a function of time, in conjunction with variation of concentration of the feed supply, shows high purity MOF-5 is produced using a continuous system, with potentially high throughput on scale up. We also show that the output can be increased by increasing the concentration of reactants in the system, albeit resulting in a reduced surface area. The two most common solvents currently used for MOF-5 production are also compared to identify a more economically viable process.