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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Osatiashtiani, Amin
Aston University
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (10/10 displayed)
- 2021Formulation, adsorption performance, and mechanical integrity of triamine grafted binder-based mesoporous silica pellets for CO2 capturecitations
- 2020Monometallic and bimetallic catalysts based on Pd, Cu and Ni for hydrogen transfer deoxygenation of a prototypical fatty acid to diesel range hydrocarbonscitations
- 2020Pompon Dahlia-like Cu2O/rGO Nanostructures for Visible Light Photocatalytic H2 Production and 4-Chlorophenol Degradationcitations
- 2020Pompon Dahlia‐like Cu2O/rGO Nanostructures for Visible Light Photocatalytic H2 Production and 4‐Chlorophenol Degradationcitations
- 2019Oxidative Thermal Sintering and Redispersion of Rh Nanoparticles on Supports with High Oxygen Ion Labilitycitations
- 2019Monometallic and bimetallic catalysts based on Pd, Cu and Ni for hydrogen transfer deoxygenation of a prototypical fatty acid to diesel range hydrocarbonscitations
- 2018A magnetically separable SO 4 /Fe-Al-TiO 2 solid acid catalyst for biodiesel production from waste cooking oil
- 2017H5PW10V2O40@VOx/SBA-15-NH2 catalyst for the solventless synthesis of 3-substituted indoles
- 2017H5PW10V2O40@VOx/SBA-15-NH2 catalyst for the solventless synthesis of 3-substituted indolescitations
- 2014Valorisation of vietnamese rice straw wastecitations
Places of action
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article
Monometallic and bimetallic catalysts based on Pd, Cu and Ni for hydrogen transfer deoxygenation of a prototypical fatty acid to diesel range hydrocarbons
Abstract
Bimetallic PdxNi(100-x) and PdxCu(100-x) structures of a wide compositional range supported on activated carbon were synthesised via a simple, cheap and commercially relevant method. The surface and bulk properties of both the bimetallic structures and their monometallic counterparts were determined via STEM-EDS, TEM, XPS, powder XRD, N2 porosimetry and ICP-OES. A close correlation between the XRD patterns and EDS elemental composition mapping of individual metal particles established the extent of palladium-base metal interaction in each sample. The performance of the different structures as catalysts for the selective hydrogenation and hydrodeoxygenation of oleic acid, a prototypical fatty acid, was evaluated using tetralin as a hydrogen donor. Catalysts displaying true bimetallic/alloy formation were found to improve the conversion of tetralin as compared to catalysts in which compositional segregation was observed. The PdxNi(100-x) series was found to outperform the PdxCu(100-x) catalysts in terms of hydrogen production via the dehydrogenation of tetralin, mirroring the fact that compositional segregation occurs more for the PdxCu(100-x) series than PdxNi(100-x). The hydrogen transfer deoxygenation of oleic acid over the monometallic and bimetallic catalysts was found to mirror the availability of hydrogen with those catalysts liberating more hydrogen also favouring the formation of C17 and C18 alkanes.