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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Marques, Ana
Instituto de Novas Tecnologias
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (11/11 displayed)
- 2023Influence of CO2 laser beam modelling on electronic and electrochemical properties of paper-based laser-induced graphene for disposable pH electrochemical sensorscitations
- 2022Passive direct methanol fuel cells acting as fully autonomous electrochemical biosensorscitations
- 2022Water Peel-Off Transfer of Electronically Enhanced, Paper-Based Laser-Induced Graphene for Wearable Electronicscitations
- 2021Production of medium-chain-length polyhydroxyalkanoates by Pseudomonascitations
- 2021Laser-Induced Graphene on Paper toward Efficient Fabrication of Flexible, Planar Electrodes for Electrochemical Sensingcitations
- 2021Tuning the Electrical Properties of Cellulose Nanocrystals through Laser-Induced Graphitization for UV Photodetectorscitations
- 2020Silver nanocomposites based on the bacterial fucose-rich polysaccharide secreted by Enterobacter A47 for wound dressing applications: Synthesis, characterization and in vitro bioactivitycitations
- 2019Demonstration of the adhesive properties of the medium-chain-length polyhydroxyalkanoate produced by Pseudomonas chlororaphis subsp. aurantiaca from glycerolcitations
- 2018Green Nanotechnology from Waste Carbon-Polyaniline Compositecitations
- 2016Smart optically active VO2 nanostructured layers applied in roof-type ceramic tiles for energy efficiencycitations
- 20168-hydroxy-2′-deoxyguanosine (8-OHdG) biomarker detection down to picoMolar level on a plastic antibody filmcitations
Places of action
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article
Influence of CO2 laser beam modelling on electronic and electrochemical properties of paper-based laser-induced graphene for disposable pH electrochemical sensors
Abstract
<p>Laser-induced graphene (LIG) allows for the fabrication of cost-effective, flexible electrodes on a multitude of recyclable and sustainable substrates, for implementation within electrochemical biosensors. This work expands on current LIG research, by experimentally modeling the effects of several CO<sub>2</sub> laser irradiation variables towards resulting conductive and electrochemical properties of paper-derived LIG. Instead of relying on the established paradigm of manipulating power and scan speed of the laser irradiation process for optimized outcomes, modeling of underlying laser operation principles for pulse modulation, regarding pulse repetition frequencies, pulse duration and defocus are presented as the key aspects dominating graphitization processes of materials. This approach shows that graphitization is dominated by appropriate pulse durations, dictating the time the substrate is exposed to each laser pulse, with laser fluence and irradiation defocus influencing the resulting conductive properties, with sheet resistances as low as 14 Ω sq<sup>−1</sup>. Similarly, fabrication settings controlled by these parameters have a direct influence on the properties of LIG-based electrochemical three-electrode cells, with optimized fabrication settings reaching electrochemically active surface area as high as 35 mm<sup>2</sup> and heterogeneous electron transfer rates of 3.4 × 10<sup>−3</sup> cm.s<sup>−1</sup>. As a proof-of-concept, the production of environmentally friendly, accessible, and biocompatible pH sensors is demonstrated, using two modification approaches, employing riboflavin and polyaniline as pH-sensitive elements.</p>