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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Kirkensgaard, Jacob, J. K.
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (11/11 displayed)
- 2024Composite material in the sea urchin Cidaris rugosacitations
- 2024Structural and physical-chemical properties of milk fat globules fractionated by a series of silicon carbide membranescitations
- 2023A Comparison of Cellulose Nanocrystals and Nanofibers as Reinforcements to Amylose-Based Composite Bioplasticscitations
- 2023Modulating Barrier Properties of Stereocomplex Polylactidecitations
- 2023Shape2SAScitations
- 2022LEO and LiMO Fuelscitations
- 2021Operando SAXS study of a Pt/C fuel cell catalyst with an X-ray laboratory sourcecitations
- 2017All-natural bio-plastics using starch-betaglucan compositescitations
- 2016Dimeric peptides with three different linkers self-assemble with phospholipids to form peptide nanodiscs that stabilize membrane proteinscitations
- 2016Plant-crafted starches for bioplastics productioncitations
- 2015Relaxation Mechanism and Molecular Structure Study of Polymer Blends by Rheological and SANS experiments
Places of action
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article
Plant-crafted starches for bioplastics production
Abstract
Transgenically-produced amylose-only (AO) starch was used to manufacture bioplastic prototypes. Extruded starch samples were tested for crystal residues, elasticity, glass transition temperature, mechanical properties, molecular mass and microstructure. The AO starch granule crystallinity was both of the B- and Vh-type, while the isogenic control starch was mainly A-type. The first of three endothermic transitions was attributed to gelatinization at about 60 °C. The second and third peaks were identified as melting of the starch and amylose-lipid complexes, respectively. After extrusion, the AO samples displayed Vh- and B-type crystalline structures, the B-type polymorph being the dominant one. The AO prototypes demonstrated a 6-fold higher mechanical stress at break and 2.5-fold higher strain at break compared to control starch. Dynamic mechanical analysis showed a significant increase in the storage modulus (E′) for AO samples compared to the control. The data support the use of pure starch-based bioplastics devoid of non-polysaccharide fillers.