693.932 PEOPLE
| People | Locations | Statistics |
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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Papageorgiou, Dimitrios G.
Queen Mary University of London
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (60/60 displayed)
- 2024Hometronics – accessible production of graphene suspensions for health sensing applications using only household items
- 2024Micromechanics of Ti3C2Tx MXene Reinforced Poly(vinyl Alcohol) Nanocompositescitations
- 2024The role of cavitation in the toughening of elastomer nanocomposites reinforced with graphene nanoplateletscitations
- 2023Smart Skins Based on Assembled Piezoresistive Networks of Sustainable Graphene Microcapsules for High Precision Health Diagnosticscitations
- 2023Smart and repeatable easy-repairing and self-sensing composites with enhanced mechanical performance for extended components life
- 2020Anisotropic swelling of elastomers filled with aligned 2D materialscitations
- 2020PMMA-grafted graphene nanoplatelets to reinforce the mechanical and thermal properties of PMMA compositescitations
- 2020Multifunctional Biocomposites Based on Polyhydroxyalkanoate and Graphene/Carbon Nanofiber Hybrids for Electrical and Thermal Applicationscitations
- 2019Sustainable thermoplastics from renewable resources:Thermal behavior of poly(1,4-cyclohexane dimethylene 2,5-furandicarboxylate)citations
- 2019Sustainable thermoplastics from renewable resourcescitations
- 2018Effect of surface functionalization of halloysite nanotubes on synthesis and thermal properties of poly(ε-caprolactone)citations
- 2018Sustainable Polymers from Renewable Resourcescitations
- 2018Sustainable Polymers from Renewable Resources:Polymer Blends of Furan-Based Polyesterscitations
- 2018Synthesis and characterization of in-situ-prepared nanocomposites based on poly(propylene 2,5-furan dicarboxylate) and aluminosilicate clayscitations
- 2018Insights into crystallization and melting of high density polyethylene/graphene nanocomposites studied by fast scanning calorimetrycitations
- 2018Synthesis and controlled crystallization of in situ prepared poly(butylene-2,6-naphthalate) nanocompositescitations
- 2018Enhanced thermal and fire retardancy properties of polypropylene reinforced with a hybrid graphene/glass-fibre fillercitations
- 2017Solid-state structure and thermal characteristics of a sustainable biobased copolymer:Poly(butylene succinate-co-furanoate)citations
- 2017Mechanical Properties of Graphene and Graphene-based Nanocompositescitations
- 2017Effect of MWCNTs and their modification on crystallization and thermal degradation of poly(butylene naphthalate)citations
- 2017Poly(ethylene furanoate-co-ethylene terephthalate) biobased copolymerscitations
- 2017Poly(ethylene furanoate-co-ethylene terephthalate) biobased copolymers:Synthesis, thermal properties and cocrystallization behaviorcitations
- 2017The mechanics of reinforcement in polymer-based nanocomposites
- 2017Solid-state structure and thermal characteristics of a sustainable biobased copolymercitations
- 2016Hybrid multifunctional graphene/glass-fibre polypropylene compositescitations
- 2016Fast Crystallization and Melting Behavior of a Long-Spaced Aliphatic Furandicarboxylate Biobased Polyester, Poly(dodecylene 2,5-furanoate)citations
- 2015Synthesis, properties and thermal behavior of poly(decylene-2,5-furanoate):A biobased polyester from 2,5-furan dicarboxylic acidcitations
- 2015Amino-functionalized multiwalled carbon nanotubes lead to successful ring-opening polymerization of poLY(ε-caprolactone)citations
- 2015β-Nucleated Polypropylene:Processing, Properties and Nanocompositescitations
- 2015Effect of clay modification on structure-property relationships and thermal degradation kinetics of β-polypropylene/clay composite materialscitations
- 2015Effect of clay modification on structure-property relationships and thermal degradation kinetics of β-polypropylene/clay composite materialscitations
- 2015Sustainable, eco-friendly polyesters synthesized from renewable resources:Preparation and thermal characteristics of poly(dimethyl-propylene furanoate)citations
- 2015Furan-based polyesters from renewable resourcescitations
- 2015β-Nucleated Polypropylenecitations
- 2015Sustainable, eco-friendly polyesters synthesized from renewable resourcescitations
- 2015Amino-functionalized multiwalled carbon nanotubes lead to successful ring-opening polymerization of poLY(ε-caprolactone):Enhanced interfacial bonding and optimized mechanical propertiescitations
- 2015Polycaprolactone/multi-wall carbon nanotube nanocomposites prepared by in situ ring opening polymerization:Decomposition profiling using thermogravimetric analysis and analytical pyrolysis-gas chromatography/mass spectrometrycitations
- 2015Graphene/Elastomer Nanocompositescitations
- 2015On the bio-based furanic polyesterscitations
- 2015Polycaprolactone/multi-wall carbon nanotube nanocomposites prepared by in situ ring opening polymerizationcitations
- 2015Synthesis of the bio-based polyester poly(propylene 2,5-furan dicarboxylate). Comparison of thermal behavior and solid state structure with its terephthalate and naphthalate homologuescitations
- 2015Furan-based polyesters from renewable resources:Crystallization and thermal degradation behavior of poly(hexamethylene 2,5-furan-dicarboxylate)citations
- 2015Synthesis, properties and thermal behavior of poly(decylene-2,5-furanoate)citations
- 2015On the bio-based furanic polyesters:Synthesis and thermal behavior study of poly(octylene furanoate) using fast and temperature modulated scanning calorimetrycitations
- 2014Effect of clay structure and type of organomodifier on the thermal properties of poly(ethylene terephthalate) based nanocompositescitations
- 2014Effect of clay structure and type of organomodifier on the thermal properties of poly(ethylene terephthalate) based nanocompositescitations
- 2014Evaluation of polyesters from renewable resources as alternatives to the current fossil-based polymers. Phase transitions of poly(butylene 2,5-furan-dicarboxylate)citations
- 2014Thermal degradation kinetics and decomposition mechanism of PBSu nanocomposites with silica-nanotubes and strontium hydroxyapatite nanorodscitations
- 2014Effect of silica nanoparticles modification on the thermal, structural, and decomposition properties of a β-nucleated poly(propylene-co-ethylene) matrixcitations
- 2014Synergistic effect of functionalized silica nanoparticles and a β-nucleating agent for the improvement of the mechanical properties of a propylene/ethylene random copolymercitations
- 2014β-nucleated propylene-ethylene random copolymer filled with multi-walled carbon nanotubes:Mechanical, thermal and rheological propertiescitations
- 2014β-nucleated propylene-ethylene random copolymer filled with multi-walled carbon nanotubescitations
- 2014Effect of nanofiller's size and shape on the solid state microstructure and thermal properties of poly(butylene succinate) nanocompositescitations
- 2014Crystallization and melting behavior of poly(butylene succinate) nanocomposites containing silica-nanotubes and strontium hydroxyapatite nanorodscitations
- 2014Kinetics of nucleation and crystallization in poly(butylene succinate) nanocompositescitations
- 2013Crystallization and melting of propylene-ethylene random copolymers. Homogeneous nucleation and β-nucleating agentscitations
- 2013Competitive crystallization of a propylene/ethylene random copolymer filled with a β-nucleating agent and multi-walled carbon nanotubes. conventional and ultrafast DSC studycitations
- 2013Isotactic polypropylene/multi-walled carbon nanotube nanocomposites:The effect of modification of MWCNTs on mechanical properties and melt crystallizationcitations
- 2013Isotactic polypropylene/multi-walled carbon nanotube nanocompositescitations
- 2012Effect of crystalline structure of polypropylene random copolymers on mechanical properties and thermal degradation kineticscitations
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article
PMMA-grafted graphene nanoplatelets to reinforce the mechanical and thermal properties of PMMA composites
Abstract
In order to realise the potential of graphene nanocomposites it is vital to control the degree of dispersion and achieve a strong graphene/polymer interface. Herein, we developed a facile ‘grafting to’ functionalization approach for graphene nanoplatelets. NH 2 -terminated graphene nanoplatelets (NH 2 -GNPs) prepared by diazonium coupling were used as a ‘platform’ to covalently graft PMMA chains to the surface of graphene through amidation between the –NH 2 groups and PMMA chains (PMMA–NH–GNPs). A degree of PMMA grafting of ∼3.8 wt% (one chain per ∼40 carbon atoms) was found to both improve the dispersion of the GNPs in a PMMA matrix and give strong graphene/polymer interfaces compared to as-provided GNPs. Thus, 2 wt% of PMMA–NH–GNPs in PMMA was found to increase the elastic modulus, strength and strain at break of PMMA, whereas the incorporation of unmodified GNPs showed poor levels of reinforcement at all loadings. Furthermore, the glass transition temperature (T g )and the onset of decomposition (T d ) of PMMA were increased by 15 °C and 29 °C, respectively, by adding 5 wt% of PMMA–NH–GNPs, whereas incorporating unmodified GNPs led to smaller increases. This work offers the possibility of controlling the properties of graphene/polymer composites through chemically tuning the graphene/polymer interface, which will have broad implications in the field of nanocomposites.