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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Bonaccorso, Francesco
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (30/30 displayed)
- 2024Engineering of perovskite/electron-transporting layer interface with transition metal chalcogenides for improving the performance of inverted perovskite solar cellscitations
- 2024Venice’s macroalgae-derived active material for aqueous, organic, and solid-state supercapacitorscitations
- 2024Coexistence of Redox‐Active Metal and Ligand Sites in Copper‐based 2D Conjugated Metal‐Organic Frameworks for Battery‐Supercapacitor hybrid systemscitations
- 2023Current collectors based on multiwalled carbon-nanotubes and few-layer graphene for enhancing the conversion process in scalable lithium-sulfur batterycitations
- 2023Water‐based supercapacitors with amino acid electrolytes: a green perspective for capacitance enhancementcitations
- 2023Influence of Ion Diffusion on the Lithium-Oxygen Electrochemical Process and Battery Application Using Carbon Nanotubes-Graphene Substratecitations
- 2022Highly Efficient 2D Materials Engineered Perovskite/Si Tandem Bifacial Cells Beyond 29%citations
- 2022Enhancing charge extraction in inverted perovskite solar cells contacts <i>via</i> ultrathin graphene:fullerene composite interlayerscitations
- 2022Highly Efficient 2D Materials Engineered Perovskite/Si Tandem Bifacial Cells Beyond 29%.citations
- 2022Carbon-α-Fe2O3 Composite Active Material for High-Capacity Electrodes with High Mass Loading and Flat Current Collector for Quasi-Symmetric Supercapacitorscitations
- 2022Few-Layers Graphene-Based Cement Mortars: Production Process and Mechanical Propertiescitations
- 2021Inverted perovskite solar cells with enhanced lifetime and thermal stability enabled by a metallic tantalum disulfide buffer layercitations
- 2020Microwave-Induced Structural Engineering and Pt Trapping in 6R-TaS2 for the Hydrogen Evolution Reactioncitations
- 2020Production and processing of graphene and related materials
- 2020Production and processing of graphene and related materialscitations
- 2020Production and processing of graphene and related materialscitations
- 2020Production and processing of graphene and related materialscitations
- 2020Production and processing of graphene and related materialscitations
- 2020Production and processing of graphene and related materialscitations
- 2020Production and processing of graphene and related materialscitations
- 2020Production and processing of graphene and related materialscitations
- 2020Production and processing of graphene and related materials
- 2019Scalable Production of Graphene Inks via Wet‐Jet Milling Exfoliation for Screen‐Printed Micro‐Supercapacitorscitations
- 2019Extending the Colloidal Transition Metal Dichalcogenide Library to ReS2 Nanosheets for Application in Gas Sensing and Electrocatalysiscitations
- 2018Graphene-engineered automated sprayed mesoscopic structure for perovskite device scaling-upcitations
- 2017Spider silk reinforced by graphene or carbon nanotubescitations
- 2016Effect of graphene nano-platelet morphology on the elastic modulus of soft and hard biopolymerscitations
- 2016Effect of graphene nano-platelet morphology on the elastic modulus of soft and hard biopolymerscitations
- 2016High surface area graphene foams by chemical vapor deposition
- 2014An advanced lithium-ion battery based on a graphene anode and a lithium iron phosphate cathodecitations
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article
Effect of graphene nano-platelet morphology on the elastic modulus of soft and hard biopolymers
Abstract
Free-standing biocomposites were fabricated by solvent casting and hot-pressing employing two bio-polyesters having diverse elastic (Young's) moduli (soft and hard), reinforced with different graphene nanoplatelets (GnPs). Systematic mechanical measurements were conducted to investigate the effect of GnP thickness and lateral size on the elastic moduli. Comparisons were made with other reinforcing nanostructured filers such as organoclay, MoS2, Fe2O3, carbon black and silica nanoparticles. Upon solvent casting, GnPs did not perform better than the other model fillers in increasing the elastic modulus of the soft bio-polyester. Upon hot-pressing however, large (>300 nm) multi-layer GnPs (≥8 layers) more than doubled the elastic modulus of the soft bio-polyester matrix compared to other GnPs and fillers. This effect was attributed to the optimized alignment of the large 2D GnP flakes within the amorphous soft polymer. In contrast, hot-pressing did not yield superior elastic modulus enhancement for the hard bio-polyester when hot-pressed. GnPs only induced 30% enhancement for both processes. Moreover, multi-layer large GnPs were shown to suppress the thermally-induced stiffness reduction of the soft bio-polyester near its melting temperature. A theoretical analysis based on the spring network model is deployed to describe the impact of the GnP alignment on the elastic moduli enhancement.