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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Sharma, Anirudh
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (21/21 displayed)
- 2022Methods of preparation of metal-doped and hybrid tungsten oxide nanoparticles for anticancer, antibacterial, and biosensing applicationscitations
- 2022Backbone-driven host-dopant miscibility modulates molecular doping in NDI conjugated polymerscitations
- 2022Backbone-driven host-dopant miscibility modulates molecular doping in NDI conjugated polymerscitations
- 2021Temperature-modulated doping at polymer semiconductor interfacescitations
- 2020p-Doping of a Hole Transport Material via a Poly(ionic liquid) for over 20% Efficiency and Hysteresis-Free Perovskite Solar Cellscitations
- 2020Water/Ethanol Soluble p-Type Conjugated Polymers for the Use in Organic Photovoltaicscitations
- 2019Probing the Relationship between Molecular Structures, Thermal Transitions, and Morphology in Polymer Semiconductors Using a Woven Glass-Mesh-Based DMTA Techniquecitations
- 2019Orange to green switching anthraquinone-based electrochromic materialcitations
- 2019Building intermixed donor-acceptor architectures for water-processable organic photovoltaicscitations
- 2018High Performance All-Polymer Photodetector Comprising a Donor–Acceptor–Acceptor Structured Indacenodithiophene–Bithieno[3,4- c ]Pyrroletetrone Copolymercitations
- 2018Engineering Two-Phase and Three-Phase Microstructures from Water-Based Dispersions of Nanoparticles for Eco-Friendly Polymer Solar Cell Applicationscitations
- 2018Engineering Two-Phase and Three-Phase Microstructures from Water-Based Dispersions of Nanoparticles for Eco-Friendly Polymer Solar Cell Applications
- 2018Environmentally friendly preparation of nanoparticles for organic photovoltaicscitations
- 2018Environmentally friendly preparation of nanoparticles for organic photovoltaicscitations
- 2018Insights into the Oxidant/Polymer Interfacial Growth of Vapor Phase Polymerized PEDOT Thin Filmscitations
- 2018High performance all-polymer photodetector comprising a donor-Acceptor-Acceptor structured indacenodithiophene-bithieno[3,4-c] pyrroletetrone copolymercitations
- 2017Optimization of the power conversion efficiency in high bandgap pyridopyridinedithiophene-based conjugated polymers for organic photovoltaics by the random terpolymer approachcitations
- 2017Unravelling the Thermomechanical Properties of Bulk Heterojunction Blends in Polymer Solar Cellscitations
- 2015Raman spectroscopy study of the transformation of the carbonaceous skeleton of a polymer-based nanoporous carbon along the thermal annealing pathwaycitations
- 2015Inducing cells to disperse nickel nanowires via integrin-mediated responsescitations
- 2011New insights into the structure of PAMAM dendrimer/gold nanoparticle nanocompositescitations
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article
Raman spectroscopy study of the transformation of the carbonaceous skeleton of a polymer-based nanoporous carbon along the thermal annealing pathway
Abstract
We report a multi-wavelength Raman spectroscopy study of the structural changes along the thermal annealing pathway of a poly(furfuryl alcohol) (PFA) derived nanoporous carbon (NPC). The Raman spectra were deconvoluted utilizing G, D, D′, A and TPA bands. The appropriateness of these deconvolutions was confirmed via recovery of the correct dispersive behaviours of these bands. It is proposed that the ID/IG ratio is composed of two parts: one associated with the extent of graphitic crystallites (the Tuinstra–Koenig relationship), and a second related to the inter-defect distance. This model was used to successfully determine the variation of the in-plane size and intra-plane defect density along the annealing pathway. It is proposed that the NPC skeleton evolves along the annealing pathway in two stages: below 1600 °C it was dominated by a reduction of in-plane defects with a minor crystallite growth, and above this temperature growth of the crystallites accelerates as the in-plane defect density approaches zero. A significant amount of transpolyacetylene (TPA)-like structures was found to be remaining even at 2400 °C. These may be responsible for resistance to further graphitization of the PFA-based carbon at higher temperatures. ; C.H. acknowledges a joint scholarship provided by China Scholarship Council (CSC) and the University of Adelaide. S.S. acknowledges the award of International Postgraduate Research Scholarship (IPRS) from the University of Adelaide. The support of the Australian Research Council’s Discovery Program (DP110101293) and Linkage Infrastructure, Equipment and Facilities Program (LE130100119) is also gratefully acknowledged.