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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Mclaughlin, James
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (27/27 displayed)
- 2024Machine Learning-Based Structural Health Monitoring Technique for Crack Detection and Localisation Using Bluetooth Strain Gauge Sensor Networkcitations
- 2018Nanostructured nitrogen doped diamond for the detection of toxic metal ions
- 2018Nanostructured nitrogen doped diamond for the detection of toxic metal ions
- 2017Novel π-conjugated iron oxide/reduced graphene oxide nanocomposites for high performance electrochemical supercapacitorscitations
- 2017Development of an embedded thin-film strain-gauge-based SHM network into 3D-woven composite structure for wind turbine bladescitations
- 2017Functional diamond like carbon (DLC) coatings on polymer for improved gas barrier performancecitations
- 2017Development of an Embedded Thin-film Strain-sensor-based SHM for Composite Tidal Turbine Blades
- 2011Structural and surface energy analysis of nitrogenated ta-C filmscitations
- 2010Effect of thin aluminum interlayer on growth and microstructure of carbon nanotubescitations
- 2010Microstructure and field emission characteristics of ZnO nanoneedles grown by physical vapor depositioncitations
- 2009Electrical and Raman spectroscopic studies of vertically aligned multi-walled carbon nanotubes.citations
- 2009Substrate effects on the microstructure of hydrogenated amorphous carbon filmscitations
- 2009Glycine Adsorption onto DLC and N-DLC Thin Films Studied by XPS and AFMcitations
- 2007Intrinsic mechanical properties of ultra-thin amorphous carbon layerscitations
- 2006Measuring the thickness of ultra-thin diamond-like carbon filmscitations
- 2005Electronic properties of a-CNx thin films : An x-ray-absorption and photoemission spectroscopy studycitations
- 2005Electronic structure and photoluminescence study of silicon doped diamond like carbon (Si:DLC) thin filmscitations
- 2005Structural investigation and gas barrier performance of diamond-like carbon based films on polymer substratescitations
- 2005Spectroscopic analysis of a-C and a-CNx films prepared by ultrafast high repetition rate pulsed laser depositioncitations
- 2004Platelet adhesion on silicon modified hydrogenated amorphous carbon films.citations
- 2004Macrophage responses to vascular stent coatings.
- 2004Electronic structure and bonding properties of Si-doped hydrogenated amorphous carbon filmscitations
- 2001Electrical characteristics of nitrogen incorporated hydrogenated amorphous carboncitations
- 2001Intrinsic stress measured on ultra-thin amorphous carbon films deposited on AFM cantileverscitations
- 2001The insulating properties of a-C:H on silicon and metal substratescitations
- 2000Nitrogen doping of amorphous DLC films by rf plasma dissociated nitrogen atom surface bombardment in a vacuumcitations
- 2000The effects of Si incorporation on the microstructure and nanomechanical properties of DLC thin filmscitations
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article
Structural investigation and gas barrier performance of diamond-like carbon based films on polymer substrates
Abstract
n this report, tetrahedral amorphous carbon (ta-C), hydrogenated amorphous carbon (a-C:H), silicon doped tetrahedral amorphous carbon (ta-C:Si:H), and silicon doped hydrogenated amorphous carbon (a-C:H:Si) films with thickness in the range 50–370 nm have been produced by PECVD (Plasma Enhanced Chemical Vapour Deposition) and FCVA ( Filtered Cathodic Vacuum Arc) techniques on Polyethylene terepthalate (PET) and polycarbonate (PC) substrates. The paper is concerned with exploring the links between the atomic structure, gas barrier performance in carbon based films deposited on polymer substrates. A range of techniques including XRR, NEXAFS, Raman, surface profilometry, nano-indentation and water vapour permeation analysis were used to analyze the microstructure and properties of the films. The intensity and area of π* peak at the C K (carbon) edge of the NEXAFS spectra was lower in the FCVA films in comparison to that of PECVD ones confirming the higher sp 3 content of FCVA films. The surface of ta-C films showed a network of micro-cracks, which is detrimental for gas barrier application. However, the surfaces of both ta-C:H:Si and a-C:H:Si silicon-incorporated films were almost free of cracks. We also found that the incorporation of Si into both types of DLC films lead to a significant reduction of water vapour transmission rate.