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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Ipser, Herbert
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (23/23 displayed)
- 2019The Ternary Bi-Mn-Sb Phase Diagram and the Crystal Structure of the Ternary Τ Phase Bi0.8MnSb0.2citations
- 2018BiMn: Synthesis, separation by centrifugation, and characterizationcitations
- 2016Experimental Investigation of the Binary Mn-Sb Phase Diagramcitations
- 2015Sn-Ag-Cu nanosolderscitations
- 2015Phase equilibria and structural investigations of the general NiAs-type in the ternary system Ni-Pt-Sncitations
- 2015AuNi3Si6 and Au2Ni4Si7: Two New Structure Types Related to the CaF2-Type Structurecitations
- 2015Thermodynamic modelling of the general NiAs-type structure: A study of first principle energies of formation for binary Ni-containing B8 compoundscitations
- 2015Experimental investigation of the ternary system Ni-Pd-Sn with special focus on the B8-type phasecitations
- 2014Phase equilibria and structural investigations of the general NiAs-type in the ternary system Ni-Sn-Tecitations
- 2014Enthalpies of formation of Cd-Pr intermetallic compounds and thermodynamic assessment of the Cd-Pr systemcitations
- 2009Synthesis and structural characterization of ternary compounds belonging to the series RE2+mNi4+mAl15+4m (RE = rare earth metal)citations
- 2009Synthesis of Single-Phase Sn3P4 by an isopiestic methodcitations
- 2007Thermodynamics and Nonstoichiometry in the D03 Compound Ni3Sb
- 2004The Al-Ni-Si phase diagram. Part II: Phase equilibria between 33.3 and 66.7 at.% Ni
- 2004Thermodynamic investigations in the lanthanum-cadmium systemcitations
- 2003Ni, Pd, or Pt as contact materials for GaSb and InSb semiconductors: Phase diagrams
- 2003The Al-Ni-Si phase diagram between 0 and 33.3 at.% Ni
- 2003Fractional site occupation of Hf5-xNbxGe4: Crystallographic investigation and thermodynamic modeling
- 2002The Ternary Compounds Pd13ln5.25Sb3.75 and Pdln1.26Sb0.74: Crystal Structure and Electronic Structure Calculationscitations
- 2002The binary system In-Ir: A new investigation of phase relationships, crystal structures, and enthalpies of mixingcitations
- 2002Contact materials for GaSb and InSb: A phase diagram approach
- 2000Phase relationships in the ternary Ga-Ni-Sb systemcitations
- 2000Al-V phase diagram between 0 and 50 atomic percent vanadium
Places of action
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article
Enthalpies of formation of Cd-Pr intermetallic compounds and thermodynamic assessment of the Cd-Pr system
Abstract
In the present study standard enthalpies of formation were measured by reaction and solution calorimetry at stoichiometric compositions of Cd 2Pr, Cd3Pr, Cd58Pr13 and Cd 6Pr. The corresponding values were determined to be -46.0, -38.8, -35.2 and -24.7 kJ/mol(at), respectively. These data together with thermodynamic data and phase diagram information from literature served as input data for a CALPHAD-type optimization of the Cd-Pr phase diagram. The complete composition range could be described precisely with the present models, both with respect to phase equilibria as well as to thermodynamic input data. The thermodynamic parameters of all intermetallic compounds were modelled following Neumann-Kopp rule. Temperature dependent contributions to the individual Gibbs energies were used for all compounds. Extended solid solubilities are well described for the low- and high-temperature modifications of Pr and also for the intermetallic compound CdPr. A quite good agreement with all viable data available from literature was found and is presented.