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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Delsante, Simona
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (31/31 displayed)
- 2024The corrosion behavior of aluminium-magnesium alloy in natural seawater: effects of the biological activity
- 2022Thermophysical Properties of Fe-Si and Cu-Pb Melts and Their Effects on Solidification Related Processescitations
- 2022Thermophysical properties of Fe-Si and Cu-Pb melts and their effects on solidification related processes
- 2020Characterization of Glass-Ceramic Sealant for Solid Oxide Fuel Cells at Operating Conditions by Electrochemical Impedance Spectroscopycitations
- 2020Characterization of Glass-Ceramic Sealant for Solid Oxide Fuel Cells at Operating Conditions by Electrochemical Impedance Spectroscopycitations
- 2019Experimental thermodynamics, surface and transport properties of liquid Ag-Ge alloyscitations
- 2017Assessing the corrosion resistance of binary Al–Sc alloys in chloride-containing environmentcitations
- 2016Effects of Sb addition on the properties of Sn-Ag-Cu/(Cu, Ni) solder systemscitations
- 2014Effect of the Rare-Earth Addition (R = Ce, Sm) on the Phase Equilibria and Microstructure of Ni-Al Alloyscitations
- 2014Thermochemical investigation of Sm-Mg alloyscitations
- 2014Enthalpies of formation of Cd-Pr intermetallic compounds and thermodynamic assessment of the Cd-Pr systemcitations
- 2014The Gd–Ni–Al system: phases formation and isothermal sections at 500°C and 800°Ccitations
- 2013Thermodynamic stability of RNi2 Laves phasescitations
- 2013Electrocatalytic activity of crystalline Ni-Co-M (M = Cr, Mn, Cu) alloys on the oxygen evolution reaction in an alkaline environmentcitations
- 2012Influence of noble metals alloying additions on the corrosion behaviour of titanium in a fluoride-containing environmentcitations
- 2012Thermodynamic study and re-assessment of the Ge-Ni systemcitations
- 2011Bulk and surface properties of liquid Sb-Sn alloyscitations
- 2011Thermochemistry of RPdAl (R = rare earth metal) intermetallics
- 2010Influence of rare earth metals on the characteristics of anodic oxide films on aluminium and their dissolution behaviour in NaOH solutioncitations
- 2009Synthesis and structural characterization of ternary compounds belonging to the series RE2+mNi4+mAl15+4m (RE = rare earth metal)citations
- 2009Thermochemistry of Pd-In, Pd-Sn and Pd-Zn alloy systemscitations
- 2009SYNTHESIS AND STRUCTURAL CHARACTERIZATION OF TERNARY COMPOUNDS BELONGING TO THE SERIES RE2+mNi4+mAl15+4m (R = RARE EARTH METAL)citations
- 2008Al-Ti-Zn System: thermochemistry of the Ti(Zn,Al)3 phases
- 2008Electrocatalytic behaviour of Co–Ni–R (R = Rare earth metal) crystalline alloys as electrode materials for hydrogen evolution reaction in alkaline mediumcitations
- 2008Effect of rare earth metals addition on the corrosion behaviour of crystalline Co-Ni alloys in alkaline solutioncitations
- 2008Phase relations of the Sm-Ni-Al ternary system at 500°C in the 40-100 at.% Al regioncitations
- 2008Calcium – Iron – Oxygencitations
- 2008Calorimetric investigations of reactive metallic systems containing Sm, Mg, Zn and P
- 2007Correlation of microstructure and catalytic activity of crystalline Ni-Co-Y alloy electrode for the hydrogen evolution reaction in alkaline solutioncitations
- 2006Phase stability and cohesive properties of Ti-Zn intermetallics: First-principles calculations and experimental resultscitations
- 2004Thermodynamic analysis and assessment of the Ce-Ni systemcitations
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article
Enthalpies of formation of Cd-Pr intermetallic compounds and thermodynamic assessment of the Cd-Pr system
Abstract
In the present study standard enthalpies of formation were measured by reaction and solution calorimetry at stoichiometric compositions of Cd 2Pr, Cd3Pr, Cd58Pr13 and Cd 6Pr. The corresponding values were determined to be -46.0, -38.8, -35.2 and -24.7 kJ/mol(at), respectively. These data together with thermodynamic data and phase diagram information from literature served as input data for a CALPHAD-type optimization of the Cd-Pr phase diagram. The complete composition range could be described precisely with the present models, both with respect to phase equilibria as well as to thermodynamic input data. The thermodynamic parameters of all intermetallic compounds were modelled following Neumann-Kopp rule. Temperature dependent contributions to the individual Gibbs energies were used for all compounds. Extended solid solubilities are well described for the low- and high-temperature modifications of Pr and also for the intermetallic compound CdPr. A quite good agreement with all viable data available from literature was found and is presented.