| People | Locations | Statistics |
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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Jensen, Anker Degn
Technical University of Denmark
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (23/23 displayed)
- 2021Characterization of oxide-supported Cu by infrared measurements on adsorbed COcitations
- 2021Promoting effect of copper loading and mesoporosity on Cu-MOR in the carbonylation of dimethyl ether to methyl acetatecitations
- 2020Structural dynamics of an iron molybdate catalyst under redox cycling conditions studied with in situ multi edge XAS and XRDcitations
- 2019Modeling of the molybdenum loss in iron molybdate catalyst pellets for selective oxidation of methanol to formaldehydecitations
- 2019Catalytic Hydropyrolysis of Biomass using Molybdenum Sulfide Based Catalyst. Effect of Promoterscitations
- 2018Characterization of free radicals by electron spin resonance spectroscopy in biochars from pyrolysis at high heating rates and at high temperaturescitations
- 2018Hydrogen assisted catalytic biomass pyrolysis for green fuels. Effect of cata-lyst in the fluid bed
- 2016Characterization of Free Radicals By Electron Spin Resonance Spectroscopy in Biochars from Pyrolysis at High Heating Rates and at High Temperatures
- 2016Characterization of Free Radicals By Electron Spin Resonance Spectroscopy in Biochars from Pyrolysis at High Heating Rates and at High Temperatures
- 2016Characterization of free radicals by electron spin resonance spectroscopy in biochars from pyrolysis at high heating rates and at high temperaturescitations
- 2016Characterization of free radicals by electron spin resonance spectroscopy in biochars from pyrolysis at high heating rates and at high temperaturescitations
- 2014In situ observation of Cu-Ni alloy nanoparticle formation by X-ray diffraction, X-ray absorption spectroscopy, and transmission electron microscopy: Influence of Cu/Ni ratiocitations
- 2014Electron microscopy study of the deactivation of nickel based catalysts for bio oil hydrodeoxygenation
- 2012Dynamic measurement of mercury adsorption and oxidation on activated carbon in simulated cement kiln flue gascitations
- 2012Catalytic Conversion of Syngas into Higher Alcohols over Carbide Catalystscitations
- 2012CO hydrogenation to methanol on Cu–Ni catalystscitations
- 2012CO hydrogenation to methanol on Cu–Ni catalysts:Theory and experimentcitations
- 2011Alkali resistant Fe-zeolite catalysts for SCR of NO with NH3 in flue gasescitations
- 2011Flame spray synthesis of CoMo/Al2O3 hydrotreating catalystscitations
- 2010Oxy-fuel combustion of solid fuelscitations
- 2009Fluidized-Bed Coating with Sodium Sulfate and PVA-TiO2, 1. Review and Agglomeration Regime Mapscitations
- 2008A review of the interference of carbon containing fly ash with air entrainment in concretecitations
- 2008Top-spray fluid bed coating: Scale-up in terms of relative droplet size and drying forcecitations
Places of action
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article
Characterization of free radicals by electron spin resonance spectroscopy in biochars from pyrolysis at high heating rates and at high temperatures
Abstract
The concentration and type of free radicals from the decay (termination stage) of pyrolysis at slow and fast heating rates and at high temperatures (above 1000°C) in biomass char have been studied. A room temperature electron spin resonance spectroscopy study was conducted on original wood, herbaceous biomass, holocelluloses, lignin and their chars, prepared at high temperatures in a wire mesh reactor, an entrained flow reactor, and a tubular reactor. The radical concentrations in the chars from the decay stage range up between 7·10<sup>16</sup> and 1.5·10<sup>18</sup> spins g<sup> -1</sup>. The results indicated that the biomass major constituents (cellulose, hemicellulose, lignin) had a minor effect on remaining radical concentrations comparedto potassium and silica contents. The higher radical concentrations in the wheat straw chars from thedecay stage of pyrolysis in the entrained flow reactor compared to the wood chars were related to the decreased mobility of potassium in the char matrix, leading to the less efficient catalytic effects of potassiumon the bond-breaking and radical re-attachments. The high Si levels in the rice husk caused an increase in the char radical concentration compared to the wheat straw because the free radicals were trapped in a char consisting of a molten amorphous silica at heating rates of 10<sup>3</sup>-10<sup>4</sup> K s<sup>-1</sup>. The experimental electron spin resonance spectroscopy spectra were analyzed by fitting to simulated data in order to identify radical types, based on g-values and line widths. The results show that at high temperatures, mostly aliphatic radicals (g = 2.0026-2.0028) and PAH radicals (g = 2.0027e2.0031) were formed.