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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Park, Mira
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Publications (6/6 displayed)
- 2022Nitrogen and Sulfur Co-Doped Graphene Quantum Dots Anchored TiO2 Nanocomposites for Enhanced Photocatalytic Activitycitations
- 2016Photoluminescent and transparent Nylon-6 nanofiber mat composited by CdSe@ZnS quantum dots and poly (methyl methacrylate)citations
- 2016Supercapacitors based on ternary nanocomposite of TiO2&Pt@graphenescitations
- 2016Nano-engineered ZnO/CeO2 dots@CNFs for fuel cell applicationcitations
- 2015Effective photocatalytic efficacy of hydrothermally synthesized silver phosphate decorated titanium dioxide nanocomposite fiberscitations
- 2002Phenotype and Genotype of Cis-AB Family in Chonnam Area
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article
Nano-engineered ZnO/CeO2 dots@CNFs for fuel cell application
Abstract
Well-dispersed ZnO(x)CeO2(1-x) nanodots@carbon nanofibers as anode catalysts for the electrooxidation of methanol were synthesized by an easy-controlled template-free method. Their structure and morphology were characterized by X-ray diffraction (XRD), high resolution transmission electron microscopy (HR-TEM), field-emission scanning electron microscopy (FESEM) equipped with rapid EDX (energy dispersive analysis of X-ray). The appealed characterization techniques specified that the obtained material is carbon nanofibers decorated by ZnO and CeO2 nanodots. The electrochemical oxidation of methanol on ZnO(x)CeO2(1-x) nanodots@CNFs modified glassy carbon electrode in alkaline solutions was systematically evaluated by cyclic voltammetry (CV) method. A detailed investigation is made for the electrocatalytic oxidation of methanol by varying methanol concentration. The corresponding current densities of ZnO(60%)CeO2(40%) nanodots@CNFs and ZnO(40%)CeO2(60%) nanodots@CNFs were 5.3 and 16.3 mA/cm2, respectively. Moreover, negative onset potential (-50 mV vs. Ag/AgCl) was observed when ZnO(40%)CeO2(60%) nanodots@CNFs were utilized, which is a superior value among the reported non-precious electrocatalysts. These results suggested cheap and effective nanomaterials as non-precious catalyst for DMFCs application and pave the way to further improve the performance in energy and environmental applications.