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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Marcus, Philippe
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (82/82 displayed)
- 2024Acetic acid additive in NaNO3 aqueous electrolyte for long-lifespan Mg-air batteriescitations
- 2024Deciphering the Formation Process of 2D to 3D Halide Perovskite Thin Films
- 2024Investigation of Iron Dissolution Mechanism in Acidic Solutions with and without Dissolved CO2—Part I: Electrochemical Impedance Spectroscopy Measurements
- 2024Molybdenum effects on the stability of passive films unraveled at the nanometer and atomic scalescitations
- 2024Hydroxyl transport mechanisms upon passivation of Cr-Fe-Co-Ni-Mo multi-principal element alloy surfaces investigated by isotopic labellingcitations
- 2023Adsorption mechanism of quaternary ammonium corrosion inhibitor on carbon steel surface using ToF-SIMS and XPScitations
- 2023Effects of Chloride Ions on Passive Oxide Films Formed on Cr-Fe-Co-Ni(-Mo) Multi-Principal Element Alloy Surfacescitations
- 2023Impact of microbial activity on the formation of a protective layer on 5083 aluminium alloy in marine environment
- 2023Corrosion inhibition at emergent grain boundaries studied by DFT for 2-mercaptobenzothiazole on bi-crystalline coppercitations
- 2023XPS study of the thermal stability of passivated NiCrFeCoMo multi‐principal element alloy surfacescitations
- 2023XPS study of the thermal stability of passivated NiCrFeCoMo multi‐principal element alloy surfacescitations
- 2023DFT Study of Cl − Ingress into Organic Self-Assembled Monolayers on Aluminumcitations
- 2023Adsorption of 2-Mercaptobenzothiazole Organic Inhibitor and its Effects on Copper Anodic Oxidation in Alkaline Environmentcitations
- 2023Early-stage surface oxidation of the equiatomic CoCrFeMnNi high entropy alloy studied in situ by XPScitations
- 2023Advanced characterization of biomineralization layer formed on Al-Mg alloy in marine environment
- 2023Mechanism of Corrosion of Cast Aluminum-Silicon Alloys in Seawater. Part 2: Characterization and Field Testing of Sol-Gel-Coated Alloys in the Adriatic Seacitations
- 2023Towards a new process to offer an eco-friendly protection of aluminium alloys
- 2023Origin of enhanced passivity of Cr–Fe–Co–Ni–Mo multi-principal element alloy surfacescitations
- 2023Effect of surface preparation by high-temperature hydrogen annealing on the passivation of Ni-20 at.% Cr alloy in sulfuric acidcitations
- 2023Effect of surface preparation by high-temperature hydrogen annealing on the passivation of Ni-20 at.% Cr alloy in sulfuric acidcitations
- 2023Effect of marine microbial activity in corrosion inhibition of 5083 aluminium alloy [Comunicação oral]
- 2022Enhanced passivity of Cr-Fe-Co-Ni-Mo multi-component single-phase face-centred cubic alloys: design, production and corrosion behaviourcitations
- 2022XPS study of oxide nucleation and growth mechanisms on a model FeCrNiMo stainless steel surfacecitations
- 2022Effect of marine microbial activity in corrosion inhibition of 5083 aluminium alloy
- 2022Can We Enhance Passivity with a Surface Finish? Spectroscopic and Electrochemical Analysis on 316L Stainless Steelcitations
- 2022Can we enhance passivity with a surface finish?citations
- 2022Influence of sodium 5-sulfosalicylate as a corrosion inhibitor in NaCl electrolyte on enhanced performances of Mg-air batteriescitations
- 2021An XPS and ToF-SIMS study of the passive film formed on a model FeCrNiMo stainless steel surface in aqueous media after thermal pre-oxidation at ultra-low oxygen pressurecitations
- 2021An XPS and ToF-SIMS study of the passive film formed on a model FeCrNiMo stainless steel surface in aqueous media after thermal pre-oxidation at ultra-low oxygen pressurecitations
- 2021In situ scanning tunneling microscopy study of 2-mercaptobenzimidazole local inhibition effects on copper corrosion at grain boundary surface terminationscitations
- 2021Atomic Scale Insight into Corrosion Inhibition: DFT Study of 2-Mercaptobenzimidazole on Locally De-Passivated Copper Surfacescitations
- 2021Localized corrosion induced surface modifications of Al-Cu-Li alloy studied by ToF-SIMS 3D imagingcitations
- 2021Corrosion inhibition of locally de-passivated surfaces by DFT study of 2-mercaptobenzothiazole on coppercitations
- 2021Effect of Cr Content on Corrosion Resistance of Low-Cr Alloy Steels Studied by Surface and Electrochemical Techniquescitations
- 2021Local Effects of Organic Inhibitor Molecules on Passivation of Grain Boundaries Studied In Situ on Coppercitations
- 2021Nanoscale early oxidation mechanisms of model FeCrNi austenitic stainless steel surfaces at room temperaturecitations
- 2021Insight on passivity of high entropy alloys: thermal stability and ion transport mechanisms in the passive oxide film on CoCrFeMnNi surfacescitations
- 2020Chloride-induced alterations of the passive film on 316L stainless steel and blocking effect of pre-passivationcitations
- 20202-mercaptobenzothiazole corrosion inhibitor deposited at ultra-low pressure on model copper surfacescitations
- 2020Passivation-Induced Cr and Mo Enrichments of 316L Stainless Steel Surfaces and Effects of Controlled Pre-Oxidation
- 2020Study of the surface oxides and corrosion behaviour of an equiatomic CoCrFeMnNi high entropy alloy by XPS and ToF-SIMScitations
- 2020Passivation mechanisms and pre-oxidation effects on model surfaces of FeCrNi austenitic stainless steelcitations
- 2020Local Inhibition by 2-mercaptobenzothiazole of Early Stage Intergranular Corrosion of Copper
- 2020Insights on the Al-Cu-Fe-Mn intermetallic particles induced pitting corrosion of Al-Cu-Li alloycitations
- 2020Harnessing Atomic Layer Deposition and Diffusion to Spatially Localize Rare-Earth Ion Emitterscitations
- 2020Inhibition of Mg Corrosion by Sulfur Blocking of the Hydrogen Evolution Reaction on Iron Impuritiescitations
- 2019XPS and ToF-SIMS characterization of the surface oxides on lean duplex stainless steel – Global and local approachescitations
- 2019Mechanisms of Cr and Mo Enrichments in the Passive Oxide Film on 316L Austenitic Stainless Steelcitations
- 2019Influence of post-treatment time of trivalent chromium protection coating on aluminium alloy 2024-T3 on improved corrosion resistancecitations
- 2019Origin of nanoscale heterogeneity in the surface oxide film protecting stainless steel against corrosioncitations
- 2018Nanoscale Intergranular Corrosion and Relation with Grain Boundary Character as Studied In Situ on Coppercitations
- 2018Progress in corrosion science at atomic and nanometric scalescitations
- 2018New insight on early oxidation stages of austenitic stainless steel from in situ XPS analysis on single-crystalline Fe–18Cr–13Nicitations
- 2018The effect of Na2S additive in alkaline electrolyte on improved performances of Fe-based air batteriescitations
- 2017Use of local electrochemical methods (SECM, EC-STM) and AFM to differentiate microstructural effects (EBSD) on very pure coppercitations
- 2017Use of local electrochemical methods (SECM, EC-STM) and AFM to differentiate microstructural effects (EBSD) on very pure coppercitations
- 2017Effect of high temperature oxidation process on corrosion resistance of bright annealed ferritic stainless steelcitations
- 2016BSA adsorption on a plasma-deposited silver nanocomposite film controls silver release: a QCM and XPS-based modellingcitations
- 2016The role of surface preparation in corrosion protection of copper with nanometer-thick ALD alumina coatingscitations
- 2015Plasma-deposited nanocomposite polymer-silver coating against Escherichia coli and Staphylococcus aureus: antibacterial properties and ageingcitations
- 2015Influence of extracellular polymeric substances (EPS) from Pseudomonas NCIMB 2021 on the corrosion behaviour of 70Cu–30Ni alloy in seawatercitations
- 2014Interface control of atomic layer deposited oxide coatings by filtered cathodic arc deposited sublayers for improved corrosion protectioncitations
- 2014Sealing of Hard CrN and DLC Coatings with Atomic Layer Depositioncitations
- 2014Effect of protein adsorption on the corrosion behavior of 70Cu-30Ni alloy in artificial seawatercitations
- 2013Tantalum oxide nanocoatings prepared by atomic layer and filtered cathodic arc deposition for corrosion protection of steelcitations
- 2013Diaminoethane adsorption and water substitution on hydrated TiO2: a thermochemical study based on first-principles calculationscitations
- 2013AlxTayOz Mixture Coatings Prepared Using Atomic Layer Deposition for Corrosion Protection of Steelcitations
- 2013Hydrogen-argon plasma pre-treatment for improving the anti-corrosion properties of thin Al2O3 films deposited using atomic layer deposition on steelcitations
- 2011Failure mechanism of thin Al2O3 coatings grown by atomic layer deposition for corrosion protection of carbon steelcitations
- 2011Corrosion Protection of Steel with Oxide Nanolaminates Grown by Atomic Layer Depositioncitations
- 2011Electrochemical and time-of-flight secondary ion mass spectrometry analysis of ultra-thin metal oxide (Al2O3 and Ta2O5) coatings deposited by atomic layer deposition on stainless steelcitations
- 2011Electrochemical and time-of-flight secondary ion mass spectrometry analysis of ultra-thin metal oxide (Al2O3 and Ta2O5) coatings deposited by atomic layer deposition on stainless steelcitations
- 2011Low-temperature atomic layer deposition of Al2O3 thin coatings for corrosion protection of steelcitations
- 2010Electrochemical reactivity, surface composition and corrosion mechanisms of the complex metallic alloy Al 3 Mg 2citations
- 2009A preliminary quantitative XPS study of the surface films formed on pure magnesium and on magnesium-aluminium intermetallics by exposure to high-purity watercitations
- 2009Atomistic modeling of voiding mechanisms at oxide/alloy interfacescitations
- 2009Plasma-Mediated Modification of Austenitic Stainless Steel: Application to the Prevention of Yeast Adhesioncitations
- 2009A first quantitative XPS study of the surface films formed, by exposure to water, on Mg and on the Mg-Al intermetallics: Al 3 Mg 2 and Mg 17 Al 12citations
- 2008Li-ion intercalation in thermal oxide thin films of MoO3 as studied by XPS, RBS, and NRAcitations
- 2007Ageing of V2O5 thin films induced by Li intercalation multi-cyclingcitations
- 2007Estimation of the parameters of oxide film growth on nickel-based alloys in high-temperature water electrolytescitations
- 2005Effect of platinum on the growth rate of the oxide scale formed on cast nickel aluminide intermetallic alloyscitations
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article
An XPS and ToF-SIMS study of the passive film formed on a model FeCrNiMo stainless steel surface in aqueous media after thermal pre-oxidation at ultra-low oxygen pressure
Abstract
<p>A combined X-ray photoelectron spectroscopy, time-of-fight secondary ion mass spectrometry and electrochemical approach was used to investigate the mechanisms of molybdenum and chromium enrichment of a passive film formed on a model austenitic stainless steel single crystal in aqueous acid media and the effect that thermal pre-oxidation at 250°C plays in the composition, thickness and stratification of the film. A clean FeCrNiMo (1 0 0)-oriented surface, prepared under ultra-high vacuum (UHV), was exposed to ultra-low pressures of oxygen at 250°C, forming a thin oxide film, rich in iron and chromium, as well as containing molybdenum. An argon-filled glovebox, directly attached to the UHV system, allowed for electrochemical alterations to be carried out without exposure to ambient air. After being held at open circuit potential for 30 min, hydroxylation of chromium and molybdenum was promoted, with a marked enrichment of both elements in the oxide film. A distinct bilayer film was observed. Anodic polarisation resulted in a significant growth of the inner layer and further enrichment of chromium. Pre-oxidation at 250°C, using an ultra-low pressure of oxygen, was found to promote protection against transient active dissolution during anodic passivation, and to cause enrichment of molybdenum in the outer layer of the passive film.</p>