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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Kosari, Ali
Thermo Fisher Scientific (Netherlands)
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (14/14 displayed)
- 2022Evaluation of the formation and protectiveness of a lithium-based conversion layer using electrochemical noisecitations
- 2022Localised aqueous corrosion of electroless nickel immersion gold-coated coppercitations
- 2022Microstructure, mechanical, and corrosion properties of Zr1-xCrxBy diboride alloy thin films grown by hybrid high power impulse/DC magnetron co-sputteringcitations
- 2021Editors' Choice - Dealloying-Driven Cerium Precipitation on Intermetallic Particles in Aerospace Aluminium Alloyscitations
- 2021Nanoscopic and in-situ cross-sectional observations of Li-based conversion coating formation using liquid-phase TEMcitations
- 2021Laterally-resolved formation mechanism of a lithium-based conversion layer at the matrix and intermetallic particles in aerospace aluminium alloyscitations
- 2020Dealloying-driven local corrosion by intermetallic constituent particles and dispersoids in aerospace aluminium alloyscitations
- 2020In-situ nanoscopic observations of dealloying-driven local corrosion from surface initiation to in-depth propagationcitations
- 2020Cross-sectional characterization of the conversion layer formed on AA2024-T3 by a lithium-leaching coatingcitations
- 2020Corrosion resistance of hot-dip galvanized steel in simulated soil solutioncitations
- 2020Effect of simulated brazing on the microstructure and corrosion behavior of twin roll cast AA3003citations
- 2019Characterization of the passive layer on ferrite and austenite phases of super duplex stainless steelcitations
- 2019Effect of brazing on the microstructure and corrosion behaviour of a twin roll cast Al-Mn-Fe-Si alloy system
- 2018Enhanced corrosion protection of mild steel by the synergetic effect of zinc aluminum polyphosphate and 2-mercaptobenzimidazole inhibitors incorporated in epoxy-polyamide coatingscitations
Places of action
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article
Characterization of the passive layer on ferrite and austenite phases of super duplex stainless steel
Abstract
<p>In this study, we report on a combined microscopic, analytical and electrochemical characterization of the nanoscopic passive layer on a tungsten‑molybdenum-containing super duplex stainless steel. We used scanning transmission electron microscopy/energy dispersive X-ray spectroscopy, scanning Kelvin probe force microscopy, scanning tunneling spectroscopy, and Mott–Schottky electrochemical impedance spectroscopy analysis to correlate the local chemical composition and electronic properties of passive layers on austenite and ferrite phases. The passive layer on the ferrite phase contains a higher amount of Mo, W, and Cr, which accommodates a higher nobility of ferrite and a higher local energy of the band gap compared to those on the austenite. The two aforementioned phases exhibit a different composition and semi-conductive properties of their passive layers leading to dissimilar local corrosion susceptibility. These findings are of pivotal importance in further studies of austenite and ferrite phase resolved corrosion resistance of duplex stainless steel demanding a dedicated alloying strategy.</p>