| People | Locations | Statistics |
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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Zdunek, Joanna
Warsaw University of Technology
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (34/34 displayed)
- 2023Comparison of the performance properties of commercially produced roller cone bit coatingscitations
- 2021Influence of an aluminizing process on the microstructure and tensile strength of the nickel superalloy IN 718 produced by the Selective Laser Meltingcitations
- 2021Microstructure and Thermoelectric Properties of Doped FeSi2 with Addition of B4C Nanoparticlescitations
- 2021Influence of Hydrostatic Extrusion on the Mechanical Properties of the Model Al-Mg Alloyscitations
- 2020Internal nanocrystalline structure and stiffness alterations of electrospun polycaprolactone-based mats after six months of in vitro degradation. An atomic force microscopy assaycitations
- 2019Structural and electrical studies on Ti/Al-based Au-free ohmic contact metallization for AlGaN/GaN HEMTscitations
- 2019The influence of Mg addition and hydrostatic extrusion HE on the repassivation ability of pure Al, AlMg1 and AlMg3 model alloys in 3.5 wt-% NaClcitations
- 2019Microstructure and thermoelectric properties of p and n type doped β-FeSi2 fabricated by mechanical alloying and pulse plasma sinteringcitations
- 2019New approach to amorphization of alloys with low glass forming ability via selective laser meltingcitations
- 2019Analysis of residual stress in 1.4539 austenitic steel joints welded with TIG method
- 2019Texture, residual stresses and mechanical properties analysis in the commercial 1.4462 duplex stainless steel subjected to hydrostatic extrusioncitations
- 2019The influence of combined hydrostatic extrusion and rolling on the microstructure, texture and mechanical properties of Al-Li alloyscitations
- 2018The crossed – lamellar structure of mollusk shells as biocomposite material
- 2018Formation of the Nitrided Layers on an Austenitic Stainless Steel with Different Grain Structurescitations
- 2018The Influence of Selective Laser Melting (SLM) Process Parameters on In-Vitro Cell Responsecitations
- 2018Effect of structure on corrosion resistance of Mg-Zn-Ca alloy
- 2017Microstructure and strain-stress analysis of the dynamic strain aging in inconel 625 at high temperature citations
- 2017Microstructure and mechanical properties investigation of CP titanium processed by selective laser melting (SLM)citations
- 2017Influence of hydrostatic extrusion process on the microstructure and texture of polycrystalline nickelcitations
- 2017The effect of current types on the microstructure and corrosion properties of Ni/NANOAl2O3 composite coatings
- 2017Heterogeneity of deformation in duplex stainless steel subjected to hydrostatic extrusion
- 2016Synthesis of the RGO/Al2O3 core-shell nanocomposite flakes and characterization of their unique electrostatic properties using zeta potential measurementscitations
- 2016Evolution of microstructure and precipitates in 2xxx aluminum alloy after severe plastic deformationcitations
- 2016Influence of the corrosive environment on the Portevin–Le Chatelier plastic instability phenomenon in Al–1Mg and Al–3Mg model alloys
- 2016Microwave Plasma Chemical Vapor Deposition of SbxOy/C negative electrodes and their compatibility with lithium and sodium Hückel salts - Based, tailored electrolytescitations
- 2016Microstructure evolution and texture development in a Cu-8.5%at. Al material subjected to hydrostatic extrusioncitations
- 2016Investigation of the degradation mechanism of catalytic wires during oxidation of ammonia processcitations
- 2015Influence of the Al (Co, Ni) layer on the corrosion resistance of a cobalt based alloy (Mar-M-509®)citations
- 2015Microstructure and Texture of Hydrostatic Extrusion Deformed Ni Single Crystals and Polycrystalcitations
- 2014Electrochemical and cellular behavior of ultrafine-grained titanium in vitrocitations
- 2014Influence of casting method and heat treatment for corrosion resistance of magnesium alloy AZ91D
- 2013Investigation of degradation mechanism of palladium-nickel wires during oxidation of ammoniacitations
- 2013Analysis of two catalytic systems PtRhPd-PdAu and PtRh-PdAu after long-term exploitation
- 2006Influence of severe plastic deformation on the PLC effect and mechanical properties in Al 5XXX alloy
Places of action
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article
Investigation of the degradation mechanism of catalytic wires during oxidation of ammonia process
Abstract
The most common catalysts for the ammonia oxidation process are 80 μm diameter platinum-rhodium wires knitted or woven into the form of a gauze. In an aggressive environment and under extreme conditions (temperature 800–900 °C, intensive gas flow, high pressure) precious elements are drained from the surface of the wires. Part of this separated material quickly decomposes on the surface in the form of characteristic “cauliflower-shape protrusions”. The rest of the platinum is captured by palladium-nickel catalytic-capture gauzes located beneath. In our investigation we focused on the effects of the degradation of gauzes from one industrial catalytic system. The aim of the study was to compare the degree and the mechanism of degradation of gauzes from a different part of the reactor. The study covered PtRh7 catalytic and PdNi5 catalytic-capture gauzes. X-ray computer microtomography investigation revealed that despite strong differences in morphology, each Pt-Rh wire has a similar specific surface area. This indicates that the oxidation process and morphological changes of the wires occur in a self-regulating balance, resulting in the value of the specific surface area of the catalyst. Microtomography analysis of Pd-Ni wires revealed strong redevelopment of the wires’ surface, which is related to the platinum capture phenomenon. Scanning electron microscope observations also revealed the nanostructure in the cauliflower-shape protrusions and large grains in the wires’ preserved cores. The high temperature in the reactor and the long-term nature of the process do not favor the occurrence of the nanostructure in this type of material. Further and detailed analysis of this phenomena will provide a better understanding of the precious metals etching and deposition processes during oxidation.