• Vuorilehto, K.
• Karppinen, J.
• Skogström, L.
• Laurila, Tomi
• Nisula, M.
• Jalkanen, K.

Abstract

<p>Cycle aging of commercial 40. A. h pouch-type lithium-ion cells with NMC/graphite chemistry was studied at different cycling temperatures (room temperature, +45. °C, and +45. °C charge/+65. °C discharge). Aging was observed as capacity fade and resistance increase, and the aging mechanisms were characterized by electrochemical impedance spectroscopy and post-mortem analysis, where visual inspection and thickness measurements were employed together with X-ray diffraction (XRD), scanning electron microscopy (SEM), energy dispersive X-ray spectroscopy (EDS), and inductively coupled plasma optical emission spectroscopy (ICP-OES) analyses. It was observed that elevated temperatures resulted in accelerated capacity fade, especially for the +45. °C/+65. °C condition. SEI-layer growth and lithium plating, discovered in cell disassembly, were attributed to be the main mechanisms responsible for capacity loss. In addition to the capacity fade, resistance increase was observed both in ohmic and polarization resistances. The ohmic resistance growth was attributed to lack of electrolyte and increased separator resistance. Polarization resistance evolution during cycling was similar at room temperature and at +45. °C, but different at the +45. °C/+65. °C condition. It was concluded that post-mortem analysis is essential for attributing the cycle testing and impedance spectroscopy results to different components and processes inside the cell. For example, the lithium plating phenomenon could not have been predicted or discovered without disassembling the cells.</p>

Topics

• impedance spectroscopy
• scanning electron microscopy
• x-ray diffraction
• Lithium
• aging
• Energy-dispersive X-ray spectroscopy
• aging
• atomic emission spectroscopy