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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Puech, Pascal
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (15/15 displayed)
- 2024Probing Prismatic/Basal Surfaces of Carbon Materials upon Graphitization by Gas Adsorption, TPD, and XPScitations
- 20222D (< 10 nm) sp3-C-rich carbon materials, possibly hydrogenated: A reviewcitations
- 2022An embedded interfacial network stabilizes inorganic CsPbI3 perovskite thin filmscitations
- 2022An embedded interfacial network stabilizes inorganic CsPbI3 perovskite thin filmscitations
- 2020Mo thio and oxo-thio molecular complexes film as self-healing catalyst for photocatalytic hydrogen evolution on 2D materialscitations
- 2019Indirect tail states formation by thermal-induced polar fluctuations in halide perovskitescitations
- 2019Indirect tail states formation by thermal-induced polar fluctuations in halide perovskitescitations
- 2017Advanced spectroscopic analyses on a:C-H materials: Revisiting the EELS characterization and its coupling with multi-wavelength Raman spectroscopycitations
- 2015Theoretical study of graphene doping mechanism by iodine moleculescitations
- 2013The effect of twin screw extrusion on structural, electrical, and rheological properties in carbon nanotube poly-ether-ether-ketone nanocompositescitations
- 2013The preparation of carbon nanotube (CNT)/copper composites and the effect of the number of CNT walls on their hardness, friction and wear propertiescitations
- 2012Silicon nanoparticle/carbon nanotube composites for LI-ION battery anodes
- 2011Electrical conductivity and Raman imaging of double wall carbon nanotubes in a polymer matrixcitations
- 2005Spectroscopic detection of carbon nanotube interaction with amphiphilic molecules in epoxy resin compositescitations
- 2002Chirality of internal metallic and semiconducting carbon nanotubescitations
Places of action
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article
Mo thio and oxo-thio molecular complexes film as self-healing catalyst for photocatalytic hydrogen evolution on 2D materials
Abstract
2D semiconducting nanosheets of Transition Metal Dichalcogenides are attractive materials for solar energy conversion because of their unique absorption properties. Here, we show that Mo thio- and oxo-thio-complexes anchored on 2D p-WSe2 nanosheets considerably boost water splitting under visible light irradiation with photocurrent density up to 2.0 mA cm−2 at -0.2 V/NHE. Besides developing high electro-catalytic activity, the Mo-complexes film is also shown to be capable of healing surface defects. We propose that the observed healing of surface defects arises from the strong adsorption on point defects of the 2D WSe2 substrate of Mo complexes such as (MoS4)2-, (MoOS3)2-, (Mo2S6O2)2- as supported by DFT calculations. In addition, the thio-, oxo-thio Mo complexes films are shown to enhance charge carrier separation and migration favouring the hydrogen evolution reaction, putting forward the use of thio-, oxo-thio-Mo complexes as a multicomponent passivation layer exhibiting multiple properties.