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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Wark, Michael
Institute of Physical Chemistry
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (26/26 displayed)
- 2024A sustainable CVD approach for ZrN as a potential catalyst for nitrogen reduction reaction
- 2024Influence of Annealing Temperature on the OER Activity of NiO(111) Nanosheets Prepared via Microwave and Solvothermal Synthesis Approachescitations
- 2024Effect of Non-ionic Surfactant on Fe-N-C Catalyst Layers under HT-PEMFC Conditions
- 2024Benchmark of J55 and X56 steels on cracking and corrosion effects under hydrogen salt cavern boundary conditionscitations
- 2023How Effective Is Graphitization of Biomasses for the Carbon Stability of Pt/C ORR Catalysts?citations
- 2023Sol gel synthesis of defect-pyrochlore structured CsTaWO6 and the tribochemical influences on photocatalytic activity
- 2023Impact of the Water Management on the Performance Stability of Polyimidazolium-based (Aemion+®) Anion Exchange Membrane Fuel Cells
- 2021Chemical Vapor Deposition of Cobalt and Nickel Ferrite Thin Films:Investigation of Structure and Pseudocapacitive Propertiescitations
- 2021In Situ Synthesis of Co 3 O 4 /CoFe 2 O 4 Derived from a Metal–Organic Framework on Nickel Foam: High-Performance Electrocatalyst for Water Oxidationcitations
- 2021Chemical vapor deposition of cobalt and nickel ferrite thin films
- 2021Chemical Vapor Deposition of Cobalt and Nickel Ferrite Thin Films: Investigation of Structure and Pseudocapacitive Propertiescitations
- 2020Correction: Micro-spectroscopy of HKUST-1 metal–organic framework crystals loaded with tetracyanoquinodimethane: effects of water on host–guest chemistry and electrical conductivity
- 2019Micro-spectroscopy of HKUST-1 metal-organic framework crystals loaded with tetracyanoquinodimethane: effects of water on host-guest chemistry and electrical conductivitycitations
- 2019Micro-spectroscopy of HKUST-1 metal-organic framework crystals loaded with tetracyanoquinodimethane: effects of water on host-guest chemistry and electrical conductivity
- 2018Scale-up of the electrodeposition of ZnO/Eosin Y hybrid thin films for the fabrication of flexible dye-sensitized solar cell modulescitations
- 2017Microwave-Assisted Synthesis of Perovskite SrSnO3 Nanocrystals in Ionic Liquids for Photocatalytic Applicationscitations
- 2017Photoelectrochemical and theoretical investigations of spinel type ferrites (MxFe3-xO4) for water splitting: A mini-review
- 2015New insight into calcium tantalate nanocomposite photocatalysts for overall water splitting and reforming of alcohols and biomass derivativescitations
- 2015Research Update: Photoelectrochemical water splitting and photocatalytic hydrogen production using ferrites (MFe2O4) under visible light irradiation
- 2015Low-temperature route to metal titanate perovskite nanoparticles for photocatalytic applicationscitations
- 2015Low-temperature route to metal titanate perovskite nanoparticles for photocatalytic applications
- 2015CNT-TiO(_{2-delta}) composites for improved co-catalyst dispersion and stabilized photocatalytic hydrogen production
- 2013Sol–gel synthesis of defect-pyrochlore structured CsTaWO6 and the tribochemical influences on photocatalytic activitycitations
- 2011Mesoporous tin-doped indium oxide thin films: Effect of mesostructure on electrical conductivity
- 2011Multilayered ordered mesoporous platinum/titania composite films: does the photocatalytic activity benefit from the film thickness?citations
- 2008Development of polyoxadiazole nanocomposites for high temperature polymer electrolyte membrane fuel cellscitations
Places of action
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article
Low-temperature route to metal titanate perovskite nanoparticles for photocatalytic applications
Abstract
<p>MTiO<sub>3</sub> (M=Ca, Sr, Ba) nanoparticles were synthesized by a one-step room-temperature ultrasound synthesis in ionic liquid. The obtained samples are characterized by X-ray diffraction, scanning electron microscopy, nitrogen adsorption, UV-vis diffuse reflectance, Raman and IR spectroscopy and their capability in photocatalytic hydrogen evolution and methylene blue degradation was tested. Powder X-ray diffraction and Raman spectroscopic investigations revealed the products to crystallize in the cubic perovskite structure. SEM observations showed that the obtained CaTiO<sub>3</sub> consists of nanospheres, BaTiO<sub>3</sub> of raspberry-like shaped particles of 20nm in diameter. SrTiO<sub>3</sub> particles have cubic-like morphology with an edge length varying from 100 to 300nm. SrTiO<sub>3</sub> exhibited the highest catalytic activity for photocatalytic H<sub>2</sub> evolution using only 0.025wt.% Rh as co-catalyst and for the degradation of methylene blue under UV irradiation. The influence of parameters such as synthesis method, calcination temperature, and doping with nitrogen on the morphology, crystallinity, chemical composition, and photocatalytic acivity of SrTiO<sub>3</sub> was studied. Heating the as-prepared SrTiO<sub>3</sub> to 700°C for extended time leads to a decrease in surface area and catalytic activity. Ionothermal prepared SrTiO<sub>3</sub> exhibits a higher activity than sonochemically prepared one without co-catalyst due to a synergistic effect of anatase which is present in small amount as a by-phase. After photodeposition of Rh, however, the activity is lower than that of the sonochemically prepared SrTiO<sub>3</sub>. Nitrogen-doped SrTiO<sub>3</sub> showed photocatalytic acivity under visible light irradiation.</p>