| People | Locations | Statistics |
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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Damsgaard, Christian Danvad
Technical University of Denmark
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (28/28 displayed)
- 2024Using CoCu2Ga/SiO2 to identify stability-issues in ethanol-selective Co-Cu alloyed catalysts in carbon monoxide hydrogenationcitations
- 2024Using CoCu 2 Ga/SiO 2 to identify stability-issues in ethanol-selective Co-Cu alloyed catalysts in carbon monoxide hydrogenationcitations
- 2024Using CoCu$_2$Ga/SiO$_2$ to identify stability-issues in ethanol-selective Co-Cu alloyed catalysts in carbon monoxide hydrogenation
- 2024Stable mass-selected AuTiOx nanoparticles for CO oxidationcitations
- 2024Stable mass-selected AuTiO x nanoparticles for CO oxidationcitations
- 2023Ni 5-x Ga 3+x Catalyst for Selective CO 2 Hydrogenation to MeOH :Investigating the Activity at Ambient Pressure and Low Temperature with Microreactors
- 2023Ni5-xGa3+x Catalyst for Selective CO2 Hydrogenation to MeOH
- 2022Reversible Atomization and Nano-Clustering of Pt as a Strategy for Designing Ultra-Low-Metal-Loading Catalystscitations
- 2021Characterization of oxide-supported Cu by infrared measurements on adsorbed COcitations
- 2020Reduction and carburization of iron oxides for Fischer–Tropsch synthesiscitations
- 2019Evolution of intermetallic GaPd2/SiO2 catalyst and optimization for methanol synthesis at ambient pressurecitations
- 2018Scalable Synthesis of Carbon-Supported Platinum–Lanthanide and −Rare-Earth Alloys for Oxygen Reductioncitations
- 2016Influence of gas atmospheres and ceria on the stability of nanoporous gold studied by environmental electron microscopy and in situ ptychographycitations
- 2015Intermetallic GaPd2 Nanoparticles on SiO2 for Low-Pressure CO2 Hydrogenation to Methanolcitations
- 2015Intermetallic GaPd 2 Nanoparticles on SiO 2 for Low-Pressure CO 2 Hydrogenation to Methanol:Catalytic Performance and In Situ Characterizationcitations
- 2014In situ ETEM synthesis of NiGa alloy nanoparticles from nitrate salt solutioncitations
- 2014In situ observation of Cu-Ni alloy nanoparticle formation by X-ray diffraction, X-ray absorption spectroscopy, and transmission electron microscopy: Influence of Cu/Ni ratiocitations
- 2014Intermetallic compounds of Ni and Ga as catalysts for the synthesis of methanolcitations
- 2014Intermetallic compounds of Ni and Ga as catalysts for the synthesis of methanolcitations
- 2014Electron microscopy study of the deactivation of nickel based catalysts for bio oil hydrodeoxygenation
- 2013Optical coupling in the ETEM
- 2012Origin of low temperature deactivation of Ni5Ga3 nanoparticles as catalyst for methanol synthesis
- 2011In situ environmental transmission electron microscope investigation of NiGa nanoparticle synthesis
- 2009Interfacial, electrical, and spin-injection properties of epitaxial Co2MnGa grown on GaAs(100)citations
- 2008Hybrid Spintronic Structures With Magnetic Oxides and Heusler Alloyscitations
- 2006Spin injection from epitaxial Heusler alloy thin films into InGaAs/GaAs quantum wells
- 2005Fe-contacts on InAs(100) and InP(100) characterised by conversion electron Mössbauer spectroscopycitations
- 2005Spin injection between epitaxial Co2.4Mn1.6Ga and an InGaAs quantum wellcitations
Places of action
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article
Using CoCu2Ga/SiO2 to identify stability-issues in ethanol-selective Co-Cu alloyed catalysts in carbon monoxide hydrogenation
Abstract
<p>Hydrogenation of CO to higher alcohols such as ethanol is an attractive pathway for industrial production while avoiding competition with food crops. However, thermocatalytic ethanol production from syngas is currently hindered by the lack of selective catalysts. The structural integrity of ternary-alloyed CoCu<sub>2</sub>Ga nanoparticles supported on silica was studied during thermo-catalytic CO hydrogenation. Catalysts of four different CoCu<sub>2</sub>Ga weight-loadings were tested catalytically under differential conversion, showing their different intrinsic selectivity during CO hydrogenation towards ethanol, methanol, and hydrocarbons. CoCu<sub>2</sub>Ga catalysts with 3.5 wt% and 17.8 wt% proved most and least selective towards ethanol formation, respectively. These two were studied in depth using STEM-EDX of fresh and spent samples showing different size distributions of the nanoparticles for all samples, and a change in the Co/Cu distribution of the nanoparticles from fresh to spent samples. In situ characterization using XRD, XANES, and EXAFS during CO hydrogenation supported the findings of the STEM-EDX and elucidated that the fresh more homogenous catalyst consisting of ternary CoCu<sub>2</sub>Ga nanoparticles de-alloyed into Cu-rich and CoGa-rich nanoparticles. This de-alloying was possibly driven by two factors: the metastable phase of CoCu<sub>2</sub>Ga decreasing its free energy by separating Cu and Co; and the strong interaction between Co and CO further driving a segregation. From a theoretical standpoint, Cu-Co intermetallics present the most selective catalyst to form ethanol over methane and methanol. The experimental findings presented here support the theory, although further efforts are needed to improve structural stability during the catalytic reaction.</p>