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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Simell, Pekka
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Topics
Publications (10/10 displayed)
- 2022Carbon Formation in the Reforming of Simulated Biomass Gasification Gas on Nickel and Rhodium Catalystscitations
- 2018Whisker carbon formation in catalytic steam reforming of biomass gasification gascitations
- 2018Atomic layer deposition of Ti-Nb-O thin films onto electrospun fibers for fibrous and tubular catalyst support structurescitations
- 2017Method for forming catalytic nanocoating
- 2015ALD deposition of core-shell structures onto electrospun carbon webs for PEM fuel cell MEAs
- 2011Thermal plasma-sprayed nickel catalysts in the clean-up of biomass gasification gascitations
- 2007Development of zirconia catalysts for hot gas cleanup
- 2007Solid oxide fuel cell system development in VTTcitations
- 2006Characterization and control of autothermal reformer for SOFC applications
- 2000Development of novel fixed-bed gasification for biomass residues and agrobiofuels
Places of action
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article
Whisker carbon formation in catalytic steam reforming of biomass gasification gas
Abstract
Whisker carbon formation in the steam reforming of biomass gasification gas was studied in a laboratory scale reactor using two commercial nickel catalysts, precious metal catalyst and inert materials. The synthetic feed gas contained ethylene, tar model compounds and H 2 S as impurities. Whisker carbon was formed below the reaction temperature of 700 °C on an calcium-doped nickel catalyst and below 850 °C on an undoped nickel catalyst when the feed gas contained no sulfur. With the addition of more than 50 ppmv of H 2 S in the feed gas, the whisker carbon formation was inhibited. Thermodynamic calculations were carried out to estimate the upper limit temperature for the whisker carbon formation but the calculations did not correlate well with the experimental results. One of the probable explanations for this was the high concentration of unsaturated C 2+ hydrocarbons in the feed gas.