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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Faria, Jl
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (12/12 displayed)
- 2021Light-driven oxygen evolution from water oxidation with immobilised TiO2 engineered for high performancecitations
- 2020Carbon-nanotube/TiO2 materials synthesized by a one-pot oxidation/hydrothermal route for the photocatalytic production of hydrogen from biomass derivativescitations
- 2017Synthesis of TiO2-Carbon Nanotubes through ball-milling method for mineralization of oxamic acid (OMA) by photocatalytic ozonationcitations
- 2015Synergistic effect between carbon nanomaterials and ZnO for photocatalytic water decontaminationcitations
- 2014Pore structure, interface properties and photocatalytic efficiency of hydration/dehydration derived TiO2/CNT compositescitations
- 2014Controlled surface functionalization of multiwall carbon nanotubes by HNO3 hydrothermal oxidationcitations
- 2013Photocatalytic degradation of Reactive Black 5 with TiO2-coated magnetic nanoparticlescitations
- 2013CERAMIC MEMBRANES IN HYBRID PHOTOCATALYSIS/ULTRAFILTRATION PROCESSES
- 2012Insights into UV-TiO2 photocatalytic degradation of PCE for air decontamination systemscitations
- 2012Preparation of carbon aerogel supported platinum catalysts for the selective hydrogenation of cinnamaldehydecitations
- 2012Advanced nanostructured photocatalysts based on reduced graphene oxide-TiO2 composites for degradation of diphenhydramine pharmaceutical and methyl orange dyecitations
- 2011Carbon nanotube-TiO2 thin films for photocatalytic applicationscitations
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article
Preparation of carbon aerogel supported platinum catalysts for the selective hydrogenation of cinnamaldehyde
Abstract
The selective hydrogenation of cinnamaldehyde is investigated using platinum catalysts supported on carbon aerogels with different textural and chemical properties. Despite the large amount of oxygenated surface groups introduced after the oxidation step, the original porosity of the carbon aerogels is maintained. The oxidation treatments performed on the materials are found to strongly influence the surface chemistry which in turn affects the Pt dispersion, yielding larger metal particles after the chemical modifications and the H-2 pre-treatment. The presence of mesopores and the increase of the acidic character in the carbon aerogels lead to a higher catalytic activity and selectivity towards cinnamyl alcohol when compared with that obtained for the untreated materials. A thermal treatment at 973 K is found to favor the hydrogenation of the olefinic bond when using carbon aerogels, due to the remaining oxygenated surface groups, at variance with other previously reported carbon supports (xerogels and nanotubes).