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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Bernhard, Michael Christian
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (18/18 displayed)
- 2024In situ study and assessment of the phosphorus-induced solute drag effect on the grain boundary mobility of austenitecitations
- 2024Experimental investigation and computational thermodynamics of the quaternary system Fe-C-Mn-S
- 2024On the Role of Tramp Elements for Surface Defect Formation in Continuous Casting of Steelcitations
- 2024The simple microsegregation model for steel considering MnS formation in the liquid and solid phasescitations
- 2024Critical Examination of the Representativeness of Austenite Grain Growth Studies Performed In Situ Using HT-LSCM and Application to Determine Growth-inhibiting Mechanismscitations
- 2023Grain boundary mobility of γ-Fe in high-purity iron during isothermal annealingcitations
- 2023Hot tear prediction in large sized high alloyed turbine steel parts - experimental based calibration of mechanical data and model validation
- 2023Thermodynamic modeling of the Fe-Sn system including an experimental re-assessment of the liquid miscibility gapcitations
- 2023Decomposition of γ-Fe in 0.4C-1.8Si-2.8Mn-0.5Al steel during a continuous cooling process: A comparative study using in-situ HT-LSCM, DSC and dilatometrycitations
- 2023Impurities and tramp elements in steel: Thermodynamic aspects and the application to solidification processes
- 2023Einfluss der Düsenparameter auf die Kühlbedingungen in der Sekundärkühlzone einer Brammengießanlagecitations
- 2022A Near-Process 2D Heat-Transfer Model for Continuous Slab Casting of Steelcitations
- 2022Selected metallurgical models for computationally efficient prediction of quality-related issues in continuous slab casting of steel
- 2022Experimental thermodynamics for improving CALPHAD optimizations at the Chair of Ferrous Metallurgy
- 2021Characterization of the gamma-loop in the Fe-P system by coupling DSC and HT-LSCM with complementary in-situ experimental techniquescitations
- 2021Investigations on hot tearing in a continuous slab caster: Numerical modelling combined with analysis of plant results
- 2020Experimental Study of High Temperature Phase Equilibria in the Iron-Rich Part of the Fe-P and Fe-C-P Systemscitations
- 2019High precious phase diagrams – a roadmap for a successful casting processing
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article
In situ study and assessment of the phosphorus-induced solute drag effect on the grain boundary mobility of austenite
Abstract
The solute drag effect of phosphorus (P) in the single-phase austenite (γ-Fe) region was studied under isothermal annealing conditions at temperatures of 1050 °C, 1150 °C, 1250 °C and 1350 °C. High-temperature laser scanning confocal microscopy (HT-LSCM) was used to observe and quantify in situ grain growth on the surface of three different samples containing 0.026 wt.-% P, 0.044 wt.-% P and 0.102 wt.-% P. The dependence of the arithmetic mean grain sizes on time and temperature were modeled mathematically using a simple ordinary differential equation (ODE) according to normal grain growth (NGG) theory. As no other major effects, i.e., Zener-pinning by precipitates, occurred under the selected experimental conditions, grain growth interference was only considered by grain boundary (GB) segregation of P. Thus, the total grain boundary mobility (M) was directly determined depending on the P content and isothermal annealing temperature. The fitted GB mobility values enabled the determination of an average binding energy value between impurity P atoms and grain boundaries (E0 = -1.1 - -0.6 eV) in the system. Finally, the GB segregation of P in γ-Fe was derived from the observed grain growth kinetics. The results showed reasonable agreement with calculations using segregation enthalpies from the literature.