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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Ferreirós, Pedro A.
VTT Technical Research Centre of Finland
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (16/16 displayed)
- 2024Effects of surface finishes, heat treatments and printing orientations on stress corrosion cracking behavior of laser powder bed fusion 316L stainless steel in high-temperature watercitations
- 2023Microstructure Evolution by Thermomechanical Processing in the Fe-10Al-12V Superalloy
- 2023VNbCrMo refractory high-entropy alloy for nuclear applicationscitations
- 2023Chromium-based bcc-superalloys strengthened by iron supplementscitations
- 2022Influence of precipitate and grain sizes on the brittle-to-ductile transition in Fe–Al–V bcc-L21 ferritic superalloyscitations
- 2022Study of Microstructure, Hydrogen Solubility, and Corrosion of Ta-Modified Zr–1Nb Alloys for Nuclear Applicationscitations
- 2021Effects of thermo-mechanical process on phase transitions, hydrogen solubility and corrosion of Ta-modified Zr-1Nb alloyscitations
- 2020Accurate quantitative EDS-TEM analysis of precipitates and matrix in equilibrium (α+β) Zr–1Nb alloys with Ta additioncitations
- 2019Effect of Ti additions on phase transitions, lattice misfit, coarsening, and hardening mechanisms in a Fe2AlV-strengthened ferritic alloycitations
- 2018Método innovador de ensayos de impacto en altas temperaturas aplicado en aceros al carbono
- 2018High-temperature testing in a Charpy impact pendulum using in-situ Joule heating of the specimencitations
- 2018Zirconium alloys with improved corrosion resistance and service temperature for use in the fuel cladding and core structural parts of a nuclear reactor
- 2018Efecto de la sustitución de V por Ti sobre las temperaturas de transformación de fase y el desajuste de red matriz/precipitado en la superaleación 76Fe-12Al-12V
- 2017Impact toughness transition temperature of ferritic Fe-Al-V alloy with strengthening Fe2AlV precipitatescitations
- 2017Coarsening process and precipitation hardening in Fe2AlV-strengthened ferritic Fe76Al12V12 alloycitations
- 2014Characterization of microstructures and age hardening of Fe 1-2xAlxVx alloyscitations
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article
Chromium-based bcc-superalloys strengthened by iron supplements
Abstract
Chromium alloys are being considered for next-generation concentrated solar power applications operating > 800 °C. Cr offers advantages in melting point, cost, and oxidation resistance. However, improvements in mechanical performance are needed. Here, Cr-based body-centred-cubic (bcc) alloys of the type Cr(Fe)-NiAl are investigated, leading to ‘bcc-superalloys’ comprising a bcc-Cr(Fe) matrix (β) strengthened by ordered-bcc NiAl intermetallic precipitates (β’), with iron additions to tailor the precipitate volume fraction and mechanical properties at high temperatures. Computational design using CALculation of PHAse Diagram (CALPHAD) predicts that Fe increases the solubility of Ni and Al, increasing precipitate volume fraction, which is validated experimentally. Nano-scale, highly-coherent B2-NiAl precipitates with lattice misfit ∼ 0.1% are formed in the Cr(Fe) matrix. The Cr(Fe)-NiAl A2-B2 alloys show remarkably low coarsening rate (∼102 nm3/h at 1000 °C), outperforming ferritic-superalloys, cobalt- and nickel-based superalloys. Low interfacial energies of ∼ 40/20 mJ/m2 at 1000/1200 °C are determined based on the coarsening kinetics. The low coarsening rates are principally attributed to the low solubility of Ni and Al in the Cr matrix. The alloys show high compressive yield strength of ∼320 MPa at 1000 °C. The Fe-modified alloy exhibits resistance to age softening, related to the low coarsening rate as well as the relatively stable Orowan strengthening as a function of precipitate radius. Microstructure tailoring with Fe additions offers a new design route to improve the balance of properties in “Cr-superalloys”, accelerating their development as a new class of high-temperature materials.