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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Vaughan, Gavin
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (12/12 displayed)
- 2023Denser glasses relax faster: Enhanced atomic mobility and anomalous particle displacement under in-situ high pressure compression of metallic glassescitations
- 2023Mapping the structural trends in zinc aluminosilicate glassescitations
- 20225D total scattering computed tomography reveals the full reaction mechanism of a bismuth vanadate lithium ion battery anodecitations
- 2021Hydrogen Sorption Properties of a Novel Refractory Ti-V-Zr-Nb-Mo High Entropy Alloycitations
- 2015Structural evolution in Ti-Cu-Ni metallic glasses during heating
- 2015In situ monitoring of phase transformation microstructures at Earth's mantle pressure and temperature using multi-grain XRDcitations
- 2015In situ monitoring of phase transformation microstructures at Earth's mantle pressure and temperature using multi-grain XRDcitations
- 2014Evolution of atomic structure during nanoparticle formationcitations
- 2012Structural Modulation and Phase Transitions in La2CoO4.14 Investigated by Synchrotron X-ray and Neutron Single-Crystal Diffractioncitations
- 2012Structural Modulation and Phase Transitions in La2CoO4.14 Investigated by Synchrotron X-ray and Neutron Single-Crystal Diffractioncitations
- 2011Structural and mechanical characterization of Zr58.5Ti8.2Cu14.2Ni11.4Al7.7 bulk metallic glass
- 2004Self propagating high temperature synthesis of magnesium zinc ferrites (MgxZn1-xFe2O3): Thermal imaging and time resolved X-ray diffraction experimentscitations
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article
Denser glasses relax faster: Enhanced atomic mobility and anomalous particle displacement under in-situ high pressure compression of metallic glasses
Abstract
International audience ; Despite that metallic glasses are among the most studied metallic materials, still very little is known on the evolution of their unique structural, dynamical and elastic properties under compression, owing to the difficulty to perform in-situ high pressure experiments. Coupling the brightest x-rays available in synchrotrons with cutting edge high pressure technologies, we provide direct evidence of the microscopic structural and dynamical mechanisms occurring under in-situ high pressure compression and decompression in the GPa range, from the onset of the perturbation up to a severely-deformed state. We show that while pressure promotes density increasing through quasi-elastic structural deformations, the atomic mobility exhibits a hysteresis and is enhanced up to a factor 15 even at temperatures well below the glass transition. This surprising behavior results from a competition between fast avalanche-like atomic rearrangements and slow relaxation processes triggered by an anomalous super-diffusive collective particle displacement. These results provide new insights on the effect of deformation in non-ergodic materials and support the occurrence of string-like diffusion of liquid-like atoms in metallic glasses. They explain also the macroscopic impressive rejuvenation and strain hardening reported recently under ex-situ densifications.