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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Jakob, Severin
Chalmers University of Technology
in Cooperation with on an Cooperation-Score of 37%
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Publications (7/7 displayed)
- 2024Concomitant Precipitation of Intermetallic β-NiAl and Carbides in a Precipitation Hardened Steelcitations
- 2023Evolution of nano-pores during annealing of technically pure molybdenum sheet produced from different sintered formatscitations
- 2022Tuning mechanical properties of ultrafine-grained tungsten by manipulating grain boundary chemistrycitations
- 2021Grain boundary segregation in Ni-base alloys: A combined atom probe tomography and first principles studycitations
- 2021Assessment of grain boundary cohesion of technically pure and boron micro-doped molybdenum via meso-scale three-point-bending experimentscitations
- 2017Femtosecond laser machining for characterization of local mechanical properties of biomaterialscitations
- 2017Micromechanical testing of wood samples: A new preparation route using femtosecond pulsed laser ablation
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article
Tuning mechanical properties of ultrafine-grained tungsten by manipulating grain boundary chemistry
Abstract
Tungsten is, due to a combination of high strength and good physical properties, frequently considered for high-performance applications in the harshest environments. Oftentimes its inherent brittleness and low ductility stand in the way of a successful deployment in these fields. Since tungsten has been proposed as divertor material for nuclear fusion reactors, an improvement of ductility and fracture toughness is essential. An obvious first step to increase these properties is to reduce the grain size to the ultrafine-grained regime. As this still leaves the material with a relatively low-energy intercrystalline fracture mode, this work takes a step further. With the help of doping elements, which are identified from ab-initio simulations, an attempt to increase grain boundary cohesion of ultra-fine grained tungsten to improve ductility is made. After fabrication of the doped samples from powders using severe plastic deformation, thorough microstructural investigations and extensive mechanical characterization, utilizing various small-scale testing techniques, are combined to assess the properties of the materials. We report that the addition of boron and hafnium can significantly increase the bending strength and bending ductility of ultra-fine grained tungsten. An additional heat treatment of the boron doped sample amplifies this effect even further, drastically increasing the strength and overall mechanical properties due to a combination of hardening-by-annealing and increased grain boundary segregation. Thus, an effective way to adaptively improve the mechanical properties of tungsten by manipulating grain boundary chemistry is reported, validating grain boundary segregation engineering as a powerful tool for enhancing damage tolerance in brittle materials.