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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Muralt, Paul
École Polytechnique Fédérale de Lausanne
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (11/11 displayed)
- 2023Controlled electronic and magnetic landscape in self‐assembled complex oxide heterostructurescitations
- 2023Controlled Electronic and Magnetic Landscape in Self‐Assembled Complex Oxide Heterostructurescitations
- 2022Self-Poled Heteroepitaxial Bi_(1-x) Dy_x FeO_3 Films with Promising Pyroelectric Propertiescitations
- 2022Self‐Poled Heteroepitaxial Bi(1−x)DyxFeO3 Films with Promising Pyroelectric Propertiescitations
- 2021Fabrication, Characterization, and Simulation of Glass Devices with AlN Thin-Film Transducers for Excitation of Ultrasound Resonancescitations
- 2019Effect of oxygen defects blocking barriers on gadolinium doped ceria (GDC) electro-chemo-mechanical propertiescitations
- 2016Key-features in processing and microstructure for achieving giant electrostriction in gadolinium doped ceria thin filmscitations
- 2015Dimensional and structural control of silica aerogel membranes for miniaturized motionless gas pumpscitations
- 2012Microstructure and Dielectric Properties of Piezoelectric Magnetron Sputtered w-ScxAl1-xN thin filmscitations
- 2011Combinatorial high-vacuum chemical vapor deposition of textured hafnium-doped lithium niobate thin films on sapphirecitations
- 2010Combinatorial discovery and optimization of amorphous HfO 2 –Nb 2 O 5 mixture with improved transparencycitations
Places of action
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article
Effect of oxygen defects blocking barriers on gadolinium doped ceria (GDC) electro-chemo-mechanical properties
Abstract
Some oxygen defective metal oxides, such as cerium and bismuth oxides, have recently shown exceptional electrostrictive properties that are even superior to the best performing lead-based electrostrictors, e.g. lead-magnesium-niobates (PMN). Compared to piezoelectric ceramics, electromechanical mechanisms of such materials do not depend on crystalline symmetry but on the concentration of oxygen vacancy (V Ö ) in the lattice. In this work, we investigate for the first time the role of oxygen defects configuration on the electro-chemo-mechanical properties. This is achieved by tuning the oxygen defects blocking barrier density in polycrystalline gadolinium doped ceria with known oxygen vacancy concentration, Ce 0.9 Gd 0.1 O 2- δ , δ = 0.05. Nanometric starting powders of ca. ∼12 nm are sintered in different conditions, including field assisted spark plasma sintering (SPS), fast firing and conventional method at high temperatures. These approaches allow controlling grain size and Gd-dopant diffusion, i.e. via thermally driven solute drag mechanism. By correlating the electro-chemo-mechanical properties, we show that oxygen vacancy distribution in the materials plays a key role in ceria electrostriction, overcoming the expected contributions from grain size and dopant concentration.