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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Jeangros, Quentin
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (16/16 displayed)
- 2024Ion-induced field screening as a dominant factor in perovskite solar cell operational stabilitycitations
- 2024Pizza oven processing of organohalide perovskites (POPOP): a simple, versatile and efficient vapor deposition methodcitations
- 2024A Universal Perovskite/C60 Interface Modification via Atomic Layer Deposited Aluminum Oxide for Perovskite Solar Cells and Perovskite–Silicon Tandemscitations
- 2024Alleviating nanostructural phase impurities enhances the optoelectronic properties, device performance and stability of cesium-formamidinium metal–halide perovskitescitations
- 2024Alleviating nanostructural phase impurities enhances the optoelectronic properties, device performance and stability of cesium-formamidinium metal–halide perovskitescitations
- 2024A universal perovskite/C60 interface modification via atomic layer deposited aluminum oxide for perovskite solar cells and perovskite–silicon tandemscitations
- 2023Interface passivation for 31.25%-efficient perovskite/silicon tandem solar cellscitations
- 2021Multimodal Microscale Imaging of Textured Perovskite-Silicon Tandem Solar Cells.citations
- 2021Multimodal Microscale Imaging of Textured Perovskite-Silicon Tandem Solar Cells.
- 2021Vapor transport deposition of methylammonium iodide for perovskite solar cellscitations
- 2020Instability of p-i-n perovskite solar cells under reverse biascitations
- 2018Amorphous gallium oxide grown by low-temperature PECVDcitations
- 2018A passivating contact for silicon solar cells formed during a single firing thermal annealingcitations
- 2017Enhancing the optoelectronic properties of amorphous zinc tin oxide by subgap defect passivationcitations
- 2010In situ redox cycle of a nickel–YSZ fuel cell anode in an environmental transmission electron microscopecitations
- 2010In situ redox cycle of a nickel–YSZ fuel cell anode in an environmental transmission electron microscopecitations
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article
In situ redox cycle of a nickel–YSZ fuel cell anode in an environmental transmission electron microscope
Abstract
Environmental transmission electron microscopy is used in combination with density functional theory calculations to study the redox stability of a nickel/yttria-stabilized zirconia solid oxide fuel cell anode. The results reveal that the transfer of oxygen from NiO to yttria-stabilized zirconia triggers the reduction reaction. During Ni reoxidation, the creation of a porous structure, due to mass transport, accounts for the redox instability of the Ni-based anode. Both the expansion of NiO during a redox cycle and the presence of stress in the yttria-stabilized zirconia grains are observed directly. Besides providing an understanding of the Ni–YSZ anode redox degradation, the observations are used to propose an alternative anode design for improved redox tolerance.