• Erol, Ayse
• Sarcan, Fahrettin
• Akagunduz, Eyup
• Gultekin, Berke
• Usta, Metin

Abstract

<jats:title>Abstract</jats:title><jats:p>In this work, highly ordered ZrO<jats:sub>2</jats:sub> nanotube arrays were fabricated on commercial pure Zr substrates through anodic oxidation in the water-based electrolyte at various voltages (30 V, 40 V and 50 V) for 1 h. The monoclinic- and tetragonal-ZrO<jats:sub>2</jats:sub> phases were obtained on ZrO<jats:sub>2</jats:sub> nanotubes through anodic oxidation. 13 vibration modes have been observed for the samples grown at low voltages (30 V and 40 V), which are assigned to monoclinic symmetry (7Ag + 6Bg), while—with the increasing growth voltage, the dominant phonon peak intensities associated with the monoclinic symmetry 6 times are decreased, and Eg (268 and 645 cm − 1) mode corresponding to tetragonal symmetry is observed. The nanotube array surfaces exhibited hydrophilic and super-hydrophilic behavior compared to the bare Zr surface. The elastic modulus values of ZrO<jats:sub>2</jats:sub> nanotube surfaces (14.41 GPa) were highly similar to those of bone structure (10–30 GPa) compared to bare Zr substrate (120.5 GPa). Moreover, hardness values of ZrO<jats:sub>2</jats:sub> nanotube surfaces were measured between ∼76.1 MPa and ∼ 283.0 MPa. The critical load values required to separate the nanotubes from the metal surface were measured between ∼1.6 N and ∼26.3 N. The wear resistance of the ZrO<jats:sub>2</jats:sub> nanotube arrays was improved compared to that of plain Zr substrate.</jats:p>

Topics

• impedance spectroscopy
• surface
• phase
• nanotube
• zirconium
• wear resistance
• hardness