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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Abdelghany, A. M.
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (6/6 displayed)
- 2024Improving the physical and optical characteristics of Zinc doped borate glass for bone replacementcitations
- 2023Experimental and DFT studies on the structural and optical properties of chitosan/polyvinyl pyrrolidone/ZnS nanocompositescitations
- 2023Structural, Optical and Antibacterial Activity Studies on CMC/PVA Blend Filled with Three Different Types of Green Synthesized ZnO Nanoparticlescitations
- 2023Electrical investigation and enhancement of optical, structural, and dielectric properties of flexible PVDF/LiZnVO4 nanocompositescitations
- 2022Molecular structure and optical attributes of (Na-CMC/SA) natural polymer blendcitations
- 2022Structural, Optical, Mechanical and Antibacterial Properties of MgO/Poly(Vinyl Acetate)/Poly(Vinyl Chloride) Nanocompositescitations
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article
Structural, Optical, Mechanical and Antibacterial Properties of MgO/Poly(Vinyl Acetate)/Poly(Vinyl Chloride) Nanocomposites
Abstract
<jats:title>Abstract</jats:title><jats:p>Polymeric blends and nanocomposites with improved functional properties have attracted attention worldwide for industrial applications. For food packaging applications and carrying purposes, the materials to be used should have UV blocking ability, antibacterial activity, and good mechanical properties. In this study, polyvinyl acetate (PVAc)/polyvinyl chloride (PVC) blends with optimized properties and MgO/PVAc/PVC polymer nanocomposites (PNCs) were prepared by solution casting and evaporation. Fourier transform infrared (FTIR) spectroscopy confirmed the complexation and miscibility between PVAc and PVC and their interaction with MgO nanoparticles (NP). X-ray diffraction and HR-TEM analyses showed the phase purity of MgO NP with a crystallite size of ~ 18.8 nm and their dispersion in the amorphous regions of the blend without affecting the structure of each other. UV–vis-NIR spectroscopy revealed that the band gap of the blend can be tuned by changing the added ratio of each polymer, and loading MgO NP increased the semiconducting behavior of the blend. Various optical constants such as the refractive index, absorption index, and optical dispersion parameters have been evaluated. The blend composition and effects of MgO content on the stress–strain behavior were studied. The addition of MgO to the blend enhanced the tensile modulus and strength. However, there was a corresponding decline in toughness and elongation at break. These results reflect the reinforcing effect of MgO NP, which reduces the flexibility of the polymer chains. The antibacterial activities of MgO/PVAc/PVC PNCs against <jats:italic>Staphylococcus aureus</jats:italic>, <jats:italic>Escherichia coli</jats:italic>, and <jats:italic>Candida albicans</jats:italic> fungi are studied. The improvements in optical, mechanical, and anitmicrobial properties make these nanocomposites suitable for some optical devices and in food packaging applications. </jats:p>