| People | Locations | Statistics |
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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Mulet, Xavier
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (10/10 displayed)
- 2022Biomimetic Metal-Organic Frameworks as Protective Scaffolds for Live-virus Encapsulation and Vaccine Stabilisation – TEM Staining Considerations.
- 2022Biomimetic Metal-Organic Frameworks as Protective Scaffolds for Live-virus Encapsulation and Vaccine Stabilisation – TEM Staining Considerations.
- 2022Underlying Polar and Nonpolar Modification MOF-Based Factors that Influence Permanent Porosity in Porous Liquidscitations
- 2021Underlying solvent-based factors that influence permanent porosity in porous liquidscitations
- 2019Encapsulation, Visualization and Expression of Genes with Biomimetically Mineralized Zeolitic Imidazolate Framework-8 (ZIF-8)citations
- 2017Limitations with solvent exchange methods for synthesis of colloidalfullerenescitations
- 2013Predicting properties of nanoparticles for drug delivery and tissue targeting
- 2012Predicting phase behaviour of nanostructured lipid-based self-assembled materials
- 2012Predicting complex phase behaviour of self-assembling drug delivery nanoparticles
- 2011Robust and predictive modelling of amphiphilic nanostructured nanoparticle drug delivery vehicle phase behaviour
Places of action
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article
Underlying solvent-based factors that influence permanent porosity in porous liquids
Abstract
Porous liquids (PLs) offer the potential to combine the ready handling and mature industry status of liquid absorbents, with the high permanent porosity of metal organic frameworks. To be functional, these nanocomposites need to satisfy a number of performance parameters, such as stability and viscosity of the porogen-solvent combination, avoiding solvent penetration into metal organic framework (MOF) pores, suitable capacities, and kinetics for gas sorption. In this work, we systematically investigate the component materials to elucidate the parametric space where stable photoluminescence (PL) can be generated. In this situation, deeper conclusions were able to be drawn with regard to the influence of hydrophobicity/philicity on the properties of the resulting nanocomposites. Zeolitic imidazolate frameworks (ZIFs) were combined with a range of solvents varying in steric bulk, to deliver CO2 sorption capacities as high as 4.2 mmolg−1 at 10 bar. These findings may have broader implications for future investigations of this tantalising field of nanocomposites.