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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Krishnan, Dhiya
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article
Thermal Analysis and Phase Equilibria of the Molten System Na3AlF6-NdF3-Nd2O3
Abstract
<jats:title>Abstract</jats:title><jats:p>Phase diagrams of the systems Na<jats:sub>3</jats:sub>AlF<jats:sub>6</jats:sub>-NdF<jats:sub>3</jats:sub> and (Na<jats:sub>3</jats:sub>AlF<jats:sub>6</jats:sub>-NdF<jats:sub>3</jats:sub>)<jats:sub>eut</jats:sub>-Nd<jats:sub>2</jats:sub>O<jats:sub>3</jats:sub> were experimentally determined by thermal analysis up to 60 mol.% NdF<jats:sub>3</jats:sub> and 45 mol.% Nd<jats:sub>2</jats:sub>O<jats:sub>3</jats:sub>, respectively. The Na<jats:sub>3</jats:sub>AlF<jats:sub>6</jats:sub>-NdF<jats:sub>3</jats:sub> system was found to be a simple eutectic system with the eutectic point with the following approximate coordinates: 49 mol.% NdF<jats:sub>3</jats:sub> and 905°C. This eutectic composition was then used for the thermal analysis of the (Na<jats:sub>3</jats:sub>AlF<jats:sub>6</jats:sub>-NdF<jats:sub>3</jats:sub>)<jats:sub>eut</jats:sub>-Nd<jats:sub>2</jats:sub>O<jats:sub>3</jats:sub> system. The coordinates of the eutectic point of the (Na<jats:sub>3</jats:sub>AlF<jats:sub>6</jats:sub>-NdF<jats:sub>3</jats:sub>)<jats:sub>eut</jats:sub>-Nd<jats:sub>2</jats:sub>O<jats:sub>3</jats:sub> system were found to be approximately 46 mol.% Nd<jats:sub>2</jats:sub>O<jats:sub>3</jats:sub> and 733°C. After the thermal analysis, the x-ray diffraction analysis of the solidified samples of both systems was performed. The XRD analysis of the Na<jats:sub>3</jats:sub>AlF<jats:sub>6</jats:sub>-NdF<jats:sub>3</jats:sub> system has shown the formation of two new compounds; NaNdF<jats:sub>4</jats:sub> and NdOF. The formation of NdOF is probably the product of the high-temperature hydrolysis between the moisture in the atmosphere and NdF<jats:sub>3</jats:sub>. The XRD analysis of the solidified samples of the (Na<jats:sub>3</jats:sub>AlF<jats:sub>6</jats:sub>-NdF<jats:sub>3</jats:sub>)<jats:sub>eut</jats:sub>-Nd<jats:sub>2</jats:sub>O<jats:sub>3</jats:sub> system has shown the formation of the following new compounds: NaNdF<jats:sub>4</jats:sub>, NdOF, NdAlO<jats:sub>3,</jats:sub> and NaF.</jats:p>