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Publications (1/1 displayed)

  • 2023Thermal Analysis and Phase Equilibria of the Molten System Na3AlF6-NdF3-Nd2O3citations

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Kubíková, Blanka
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Rakhmatullin, Aydar
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Šimko, František
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2023

Co-Authors (by relevance)

  • Kubíková, Blanka
  • Rakhmatullin, Aydar
  • Šimko, František
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article

Thermal Analysis and Phase Equilibria of the Molten System Na3AlF6-NdF3-Nd2O3

  • Krishnan, Dhiya
  • Kubíková, Blanka
  • Rakhmatullin, Aydar
  • Šimko, František
Abstract

<jats:title>Abstract</jats:title><jats:p>Phase diagrams of the systems Na<jats:sub>3</jats:sub>AlF<jats:sub>6</jats:sub>-NdF<jats:sub>3</jats:sub> and (Na<jats:sub>3</jats:sub>AlF<jats:sub>6</jats:sub>-NdF<jats:sub>3</jats:sub>)<jats:sub>eut</jats:sub>-Nd<jats:sub>2</jats:sub>O<jats:sub>3</jats:sub> were experimentally determined by thermal analysis up to 60 mol.% NdF<jats:sub>3</jats:sub> and 45 mol.% Nd<jats:sub>2</jats:sub>O<jats:sub>3</jats:sub>, respectively. The Na<jats:sub>3</jats:sub>AlF<jats:sub>6</jats:sub>-NdF<jats:sub>3</jats:sub> system was found to be a simple eutectic system with the eutectic point with the following approximate coordinates: 49 mol.% NdF<jats:sub>3</jats:sub> and 905°C. This eutectic composition was then used for the thermal analysis of the (Na<jats:sub>3</jats:sub>AlF<jats:sub>6</jats:sub>-NdF<jats:sub>3</jats:sub>)<jats:sub>eut</jats:sub>-Nd<jats:sub>2</jats:sub>O<jats:sub>3</jats:sub> system. The coordinates of the eutectic point of the (Na<jats:sub>3</jats:sub>AlF<jats:sub>6</jats:sub>-NdF<jats:sub>3</jats:sub>)<jats:sub>eut</jats:sub>-Nd<jats:sub>2</jats:sub>O<jats:sub>3</jats:sub> system were found to be approximately 46 mol.% Nd<jats:sub>2</jats:sub>O<jats:sub>3</jats:sub> and 733°C. After the thermal analysis, the x-ray diffraction analysis of the solidified samples of both systems was performed. The XRD analysis of the Na<jats:sub>3</jats:sub>AlF<jats:sub>6</jats:sub>-NdF<jats:sub>3</jats:sub> system has shown the formation of two new compounds; NaNdF<jats:sub>4</jats:sub> and NdOF. The formation of NdOF is probably the product of the high-temperature hydrolysis between the moisture in the atmosphere and NdF<jats:sub>3</jats:sub>. The XRD analysis of the solidified samples of the (Na<jats:sub>3</jats:sub>AlF<jats:sub>6</jats:sub>-NdF<jats:sub>3</jats:sub>)<jats:sub>eut</jats:sub>-Nd<jats:sub>2</jats:sub>O<jats:sub>3</jats:sub> system has shown the formation of the following new compounds: NaNdF<jats:sub>4</jats:sub>, NdOF, NdAlO<jats:sub>3,</jats:sub> and NaF.</jats:p>

Topics
  • impedance spectroscopy
  • compound
  • phase
  • x-ray diffraction
  • thermal analysis
  • phase diagram