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article
Structure and Magnetic Properties of Heat-Resistant Sm(Co0.796−xFe0.177CuxZr0.027)6.63 Permanent Magnets with High Coercivity
Abstract
<p>The structure and temperature stability of high-temperature permanent magnets Sm(Co<sub>0.796−x</sub>Fe<sub>0.177</sub>Cu<sub>x</sub>Zr<sub>0.027</sub>)<sub>6.63</sub> (x = 0.117 and 0.130) were studied using x-ray diffraction analysis, thermomagnetic analysis, and scanning and transmission electron microscopy. The magnets have a nanocrystalline cellular structure composed of the R2:17 cell phase, 1:5 boundary phase (27–28% by volume), and Z-phase platelets. The 1:5 phase is formed in the course of isothermal annealing at 850°C and exists in the entire temperature range from 850°C to 400°C. The Curie temperature of the R2:17 and 1:5 phases is approximately 815°C and 580°C, respectively. The magnets have the following hysteresis properties at room temperature: B<sub>r</sub> = 890–920 mT, <sub>J</sub>H<sub>c</sub> = 2.4–2.6 MA/m, <sub>B</sub>H<sub>c</sub> = 629–676 kA/m, and (BH)<sub>m</sub> = 143–159 kJ/m<sup>3</sup>. In the temperature range of 20–500°C, the temperature coefficients of B<sub>r</sub> and <sub>J</sub>H<sub>c</sub> of the magnets (x = 0.117 and 0.130) do not exceed |− 0.070| and |− 0.172|%/°C, respectively.</p>