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Kainzbauer, Peter
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article
Experimental Investigation of the Binary Mn-Sb Phase Diagram
Abstract
<p>The binary manganese-antimony (Mn-Sb) phase diagram was reinvestigated in the whole composition range using powder-XRD, DTA and SEM-EDX. The phase boundaries and melting temperatures of the ferromagnetic phases MnSb and Mn<sub>2</sub>Sb were modified by taking into account the new experimental data. Most of the reaction temperatures could be verified within a range of ±10 °C. Nevertheless, a few temperatures had to be revised, such as the eutectic reaction L → β-Mn + Mn<sub>2</sub>Sb at 893 °C and the eutectoid reaction β-Mn → α-Mn + Mn<sub>2</sub>Sb at 718 °C. The previously reported peritectic melting behavior of MnSb could be confirmed. The variation of the lattice parameters of the NiAs-(B8<sub>1</sub>) type MnSb phase with composition was determined. A revised version of the of the Mn-Sb phase diagram is presented.</p>