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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Petrov, R. H. | Madrid |
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Bih, L. |
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Casati, R. |
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Kočí, Jan | Prague |
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Ospanova, Alyiya |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Abdelfattah, Mohamed M.
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article
Enhanced optical and thermal conductivity properties of barium titanate ceramic via strontium doping for thermo-optical applications
Abstract
<jats:title>Abstract</jats:title><jats:p>In this study, we prepared a homogeneous fine powder of barium titanate (BaTiO<jats:sub>3</jats:sub>, BT) doped with different concentrations of strontium (x = 0, 0.05, 0.125, 0.15, 0.20, and 0.3) and having the composition Ba<jats:sub>1-x</jats:sub>Sr<jats:sub>x</jats:sub>TiO<jats:sub>3</jats:sub> (barium strontium titanate, BSr<jats:sub>x</jats:sub>T). XRD patterns and Rietveld refinement revealed the existence of a single tetragonal phase structure for BSrxT, x = 0–20%, and a single cubic structure for BSr30%T. The physical properties of the pure and doped mixtures were studied. The results showed that the addition of strontium to the physical properties of BaTiO<jats:sub>3,</jats:sub> including the apparent porosity, bulk density, linear shrinkage, and water absorption have been changed when increasing the Sr content. Moreover, the inclusion of 15% Sr in BaTiO<jats:sub>3</jats:sub> increases the apparent porosity and water absorption of the sample to 6.2 and 28.5%, respectively.The optical properties were investigated by Ultraviolet–visible spectroscopy and it was found that the optical band gap decreases significantly with increasing Sr concentration, from 3.10 for pure BaTiO<jats:sub>3</jats:sub> to 2.46 eV for the BSr30%T compound. The thermal conductivity measurements showed that the doping mechanism and the increased temperature have a significant effect on the thermal conductivity results of the fabricated ceramic materials. Therefore, it was found that the value of thermal conductivityincreases with increasing Sr doping and at higher temperatures. A correlated behavior of optimum values is observed in band gap energy, absorption, and thermal conductivity which can be exploited for thermo-optical applications. </jats:p>