• Germeau, Alain
• Semlal, Nawal
• Sharrock, Patrick
• Xuan, Hoan Nguyen
• Boulif, Rachid
• Sy, Hieu Pham
• Toussaint, Claudia
• Nzihou, Ange
• Minh, Doan Pham
• Sane, Abdoul Razac

Abstract

Up-to-date, solar salt (a mixture of 60 mass% NaNO3 and 40 mass% KNO3) is practically the only media for thermal energy storage (TES) in concentrated solar power (CSP). This commercial product’s utilization is limited below 550 °C to avoid an irreversible thermal decomposition. The development of new performing TES materials is decisive for the deployment of CSP technology. Our recent work reported promising results obtained with mono-alkali polyphosphate (M-PO3) as TES materials. These materials can work up to around 900 °C, but their melting point is still high, which is at least 628 °C. In order to lower their melting point, binary and ternary mixtures of alkali polyphosphates are investigated in this work. Dif- ferent mixtures made of two or three alkali polyphosphates were prepared and studied using thermal analysis methods. The most promising mixture found in this work was the ternary Li-Na-K-PO3, which contained 33.3% (mol%) of each alkali metal. This mixture can be used as a liquid TES material in the temperature range of 398 to 900 °C. The results open new prospects for the development of the thermal energy storage field.

Topics

• impedance spectroscopy
• thermal analysis
• thermal decomposition
• Alkali metal