• Kemell, Marianna Leena
• Grafov, Andriy
• Grafova, Iryna
• Lunz, Juliana N.
• Sartori, Andrea
• Visentin, Francesca
• Marques, Maria F. V.
• Aguiar, Vinicius O.

Abstract

<p>Chemically modified natural fibers were introduced into a commercial biodegradable poly(butylene adipate-co-terephthalate) (PBAT) matrix to obtain composite materials in a mini-extruder. Influence of the fiber introduction on thermal and mechanical properties of the composites were studied. A decrease of the crystallinity degree of the composites was observed upon addition of the hydrolyzed-fibers, but the addition of the acetylated ones resulted in the opposite behavior. Thermal stability of the matrix was not affected by introduction of the treated fibers. However, an improvement of mechanical properties of the composites was found by means of dynamic mechanical thermal analysis and tensile tests, particularly for those containing acetylated fibers. Scanning electron micrographs of cryofractured surfaces of the composites showed stronger adhesion of the acetylated fibers to the PBAT matrix. No interfacial gaps or signs of the fiber pullout from the matrix were observed.</p>

Topics

• surface
• composite
• thermal analysis
• crystallinity