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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Adams, Richard D.
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (4/4 displayed)
- 2005Trinuclear metal clusters with three different metal atoms from the insertion of CpCo and Cp*Rh groups into the S-S bonds of [CpFeMn(CO) 5(μ-S2)]2citations
- 2004Light-promoted addition of alkenes, dienes, C 60, and disulfur to the disulfido ligand in the complex CpMoMn(CO) 5(μ-S 2)citations
- 2004Nickel-Manganese Sulfido Carbonyl Cluster Complexes. Synthesis, Structure, and Properties of the Unusual Paramagnetic Complexes Cp2Ni 2Mn(CO)3(μ3-E)2, E = S, Secitations
- 2003New disulfido molybdenum-manganese complexes exhibit facile addition of small molecules to the sulfur atomscitations
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article
Trinuclear metal clusters with three different metal atoms from the insertion of CpCo and Cp*Rh groups into the S-S bonds of [CpFeMn(CO) 5(μ-S2)]2
Abstract
<p>Two cobalt containing products CpCoMn<sub>2</sub>(CO) <sub>6</sub>(μ<sub>3</sub>-S)<sub>2</sub>, 2 and Cp<sub>2</sub>FeCoMn(CO) <sub>3</sub>(μ<sub>3</sub>-S)<sub>2</sub>, 3 were obtained from the reaction of [CpFeMn(CO)<sub>5</sub>(μ-S<sub>2</sub>)]<sub>2</sub>, 1 with CpCo(CO)<sub>2</sub> at room temperature. The two rhodium containing products: Cp*RhMn<sub>2</sub>(CO)<sub>6</sub>(μ<sub>3</sub>-S)<sub>2</sub>, 4 (11% yield) and CpFeCp*RhMn(CO)<sub>3</sub>(μ<sub>3</sub>-S) <sub>2</sub>, 5 (9% yield), were obtained from the reaction of 1 with Cp*Rh(CO)<sub>2</sub>. Compounds 3 and 5 were characterized structurally by single crystal X-ray diffraction methods. Compounds 3 and 5 both contain triangular clusters of three different types of metal atoms and have triply bridging sulfido ligands on each side of the cluster. A mechanism for their formation from 1 is proposed.</p>