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Boswell, Erin
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article
Trinuclear metal clusters with three different metal atoms from the insertion of CpCo and Cp*Rh groups into the S-S bonds of [CpFeMn(CO) 5(μ-S2)]2
Abstract
<p>Two cobalt containing products CpCoMn<sub>2</sub>(CO) <sub>6</sub>(μ<sub>3</sub>-S)<sub>2</sub>, 2 and Cp<sub>2</sub>FeCoMn(CO) <sub>3</sub>(μ<sub>3</sub>-S)<sub>2</sub>, 3 were obtained from the reaction of [CpFeMn(CO)<sub>5</sub>(μ-S<sub>2</sub>)]<sub>2</sub>, 1 with CpCo(CO)<sub>2</sub> at room temperature. The two rhodium containing products: Cp*RhMn<sub>2</sub>(CO)<sub>6</sub>(μ<sub>3</sub>-S)<sub>2</sub>, 4 (11% yield) and CpFeCp*RhMn(CO)<sub>3</sub>(μ<sub>3</sub>-S) <sub>2</sub>, 5 (9% yield), were obtained from the reaction of 1 with Cp*Rh(CO)<sub>2</sub>. Compounds 3 and 5 were characterized structurally by single crystal X-ray diffraction methods. Compounds 3 and 5 both contain triangular clusters of three different types of metal atoms and have triply bridging sulfido ligands on each side of the cluster. A mechanism for their formation from 1 is proposed.</p>