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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Marques, Ef
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (11/11 displayed)
- 2023Interactions between Ionic Cellulose Derivatives Recycled from Textile Wastes and Surfactants: Interfacial, Aggregation and Wettability Studiescitations
- 2022Polymer/surfactant mixtures as dispersants and non-covalent functionalization agents of multiwalled carbon nanotubes: Synergism, morphological characterization and molecular picturecitations
- 2021Enhancing the dispersibility of multiwalled carbon nanotubes within starch-based films by the use of ionic surfactantscitations
- 2021Nanocomposites Prepared from Carbon Nanotubes and the Transition Metal Dichalcogenides WS2 and MoS2 via Surfactant-Assisted Dispersions as Electrocatalysts for Oxygen Reactionscitations
- 2021Carbon nanotube/graphene nanocomposites built via surfactant-mediated colloid assembly as metal-free catalysts for the oxygen reduction reactioncitations
- 2018Block Copolymers as Dispersants for Single-Walled Carbon Nanotubes: Modes of Surface Attachment and Role of Block Polydispersitycitations
- 2017Critical Role of the Spacer Length of Gemini Surfactants on the Formation of Ionic Liquid Crystals and Thermotropic Behaviorcitations
- 2013Self-Aggregation Properties of Ionic Liquid 1,3-Didecyl-2-methylimidazolium Chloride in Aqueous Solution: From Spheres to Cylinders to Bilayerscitations
- 2008Spontaneous vesicle formation in catanionic mixtures of amino acid-based surfactants: Chain length symmetry effectscitations
- 2007Interactions between gemini surfactants and polymers: Thermodynamic studiescitations
- 2004Network formation of catanionic vesicles and oppositely charged polyelectrolytes. Effect of polymer charge density and hydrophobic modificationcitations
Places of action
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article
Carbon nanotube/graphene nanocomposites built via surfactant-mediated colloid assembly as metal-free catalysts for the oxygen reduction reaction
Abstract
The development of composites from 1D and 2D nanocarbon building blocks, namely carbon nanotubes and graphene layers, with enhanced properties or novel functionalities is an emerging challenge in material science. Herein, we developed a colloid-based approach using surfactants and polymers to non-covalently functionalize multiwalled carbon nanotubes (MWNTs) and graphene nanoplatelets (GnPs), and to fabricate GnP@MWNT nanocomposites via an electrostatic-driven assembly process in aqueous solution. In the assembly process, two building methods were used and compared (bulk mixing and adapted layer-by-layer assembly), using surfactant and polymer/surfactant combinations as the dispersants for the initial nanomaterials. After their characterization by scanning electron microscopy, Raman spectroscopy and BET analysis, the nanocomposites were evaluated as electrocatalysts for the oxygen reduction reaction (ORR). Results show that the type of the dispersant (namely the presence of polymer) plays a more relevant role than the specific building method in almost all the ORR parameters. Further, the nanocomposites show selectivity toward the 2-electron pathway oxygen reduction for the electrochemical production of hydrogen peroxide. The development and optimization of further nanocomposite electrocatalysts can be pursued using this type of versatile and robust assembly method.