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Lindoy, L. F.
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Publications (3/3 displayed)
- 2011Inhibition of metal ion complexation by an N2O2-donor macrocycle by incorporation of an intramolecularly hydrogen-bonding pendant phenolic groupcitations
- 2003New Macrocyclic Ligands. XVI. Synthesis of a Series of N-Benzylated Macrocycles Incorporating N4O2-Donor setscitations
- 2001Metal ion recognition. Interaction of new oxygen-nitrogen donor macrocycles with selected transition and post-transition metal ionscitations
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article
Inhibition of metal ion complexation by an N2O2-donor macrocycle by incorporation of an intramolecularly hydrogen-bonding pendant phenolic group
Abstract
The synthesis and X-ray structure of a new pendant-arm derivative of a parent 14-membered N2O2-donor macrocycle bearing an N-substituted 6-methylene-2,4-dimethylphenol group is presented. A single crystal X-ray study shows a strong intramolecular hydrogen-bond between the pendant phenol proton and the tertiary nitrogen of the macrocyclic ring, which may inhibit its ability to bind with selected transition and post-transition metal ions.