• Dzhardimalieva, G. I.
• Pomogailo, A. D.
• Skumiel, Andrzej
• Izydorzak, M.
• Leonowicz, M.

Abstract

<p>Ferromagnetic and superparamagnetic nickel nanocrystallites, stabilized in a carbon matrix, were prepared by a three-step procedure including formation of a Ni acrylamide complex, followed by frontal polymerization and pyrolysis of the polymer at various temperatures. It was found that the procedure applied enables fabrication of magnetic beads containing metallic nanocrystallites embedded in a carbon matrix. The size of the crystallites, their morphology, volume fraction, and magnetic properties can be tailored by the pyrolysis temperature. The size of the crystallites affects their behavior in an external magnetic field, i.e., a heating process is the most effective for a sample pyrolyzed at 873 K. The revealed Hⁿ-type dependence of the temperature increase rate, (dT/dt)_t=0, on the amplitude of themagnetic field indicates the presence of both superparamagnetic and ferromagnetic particles in all the samples studied since n gt; 2. For the superparamagnetic particles, the heating mechanism is associated with Néel relaxation. For the lower values of the magnetic field amplitude, H < H₀, the relaxation losses dominate whereas for the opposite case, H gt; H₀, the magnetic hysteresis is the main source of thermal energy losses. The composites containing magnetic Ni nanocrystallites entrapped in a carbon matrix can be potentially applied for hyperthermia treatment. © The Author(s) 2011.</p>

Topics

• pyrolysis
• impedance spectroscopy
• morphology
• polymer
• Carbon
• nickel
• composite