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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Bračič, Matej
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (8/8 displayed)
- 2023Pullulan-based films impregnated with silver nanoparticles from the Fusarium culmorum strain JTW1 for potential applications in the food industry and medicinecitations
- 2022Deteriorating dispersibility of flushable wet wipes during storage: Role of fibre swelling and ionic shieldingcitations
- 2020Design of stable and new polysaccharide nanoparticles composite and their interaction with solid cellulose surfacescitations
- 2019Affinity of Serum Albumin and Fibrinogen to Cellulose, Its Hydrophobic Derivatives and Blendscitations
- 2018Modification of cellulose thin films with lysine moietiescitations
- 2012Physicochemical properties and bioactivity of a novel class of cellulosicscitations
- 2012Adsorption of carboxymethyl cellulose on polymer surfacescitations
- 2012Characterization of viscose fibers modified with 6-deoxy-6-amino cellulose sulfatecitations
Places of action
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article
Characterization of viscose fibers modified with 6-deoxy-6-amino cellulose sulfate
Abstract
<p>Cellulose viscose fibres were functionalized by novel amino cellulose sulfates (ACS), namely 6-deoxy-6-(ω-aminoethyl) amino cellulose-2,3(6)-O-sulfate (AECS), and 6-deoxy-6-(2-(bis-N′,N′-(2-aminoethyl)aminoethyl)) amino cellulose-2,3(6)-O-sulfate (BAECS). In this way an amphoteric characteristics were introduced onto cellulose viscose fibers which is extremely important by fiber applications. Whilst cellulose fibers possess only negligible carboxyl groups' content, the coating of fibers by AECS and BAECS, respectively, introduces new functional groups to the fibers; as positively-charged amino groups and negatively-charged sulfate groups. The typical functional groups within the non-coated fibers, as well in the ACS-coated fibers, were characterized by means of X-ray photoelectron spectroscopy, conductometric-, potentiometric and polyelectrolyte titrations, as well as conventionally by the spectroscopic methylene-blue method. The electro-kinetic behavior was evaluated by measuring the zeta-potential of the fibers as a function of pH. The amounts of the positive-charges (introduced protonated amino groups) determined by potentiometric titration agreed with the amounts of the positive charges determined by conductometric titration. The total amounts of negatively-charged fiber groups (sulfate and carboxyl) determined by polyelectrolyte titration were 38. 8 and 32. 1 mMol kg <sup>-1</sup> for AECS-Vis and BAECS-Vis, respectively, and these results were in accordance with the conventional methylene-blue method.</p>