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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Darr, J. A.
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (14/14 displayed)
- 2012Phase stability and rapid consolidation of hydroxyapatite-zirconia nano-coprecipitates made using continuous hydrothermal flow synthesiscitations
- 2010Measure of microhardness, fracture toughness and flexural strength of N-vinylcaprolactam (NVC)-containing glass-ionomer dental cementscitations
- 2009Effects of N-vinylpyrrolidone (NVP) containing polyelectrolytes on surface properties of conventional glass-ionomer cements (GIC)citations
- 2009Synthesis of a proline-modified acrylic acid copolymer in supercritical CO2 for glass-ionomer dental cement applicationscitations
- 2008Effects of incorporation of hydroxyapatite and fluoroapatite nanobioceramics into conventional glass ionomer cements (GIC)citations
- 2008Synthesis and characterisation of magnesium substituted calcium phosphate bioceramic nanoparticles made via continuous hydrothermal flow synthesiscitations
- 2008Modification of conventional glass-ionomer cements with N-vinylpyrrolidone containing polyacids, nano-hydroxy and fluoroapatite to improve mechanical propertiescitations
- 2008Synthesis of N-vinylpyrrolidone modified acrylic acid copolymer in supercritical fluids and its application in dental glass-ionomer cementscitations
- 2007Preparation and characterisation of controlled porosity alginate hydrogels made via a simultaneous micelle templating and internal gelation processcitations
- 2007Formation of porous natural-synthetic polymer composites using emulsion templating and supercritical fluid assisted impregnationcitations
- 2007Synthesis and characterization of grafted nanohydroxyapatites using functionalized surface agentscitations
- 2006Recent developments in processing and surface modification of hydroxyapatitecitations
- 2005Surface modification of bioceramics by grafting of tailored allyl phosphonic acidcitations
- 2003Synthesis and characterization of nano-biomaterials with potential osteological applicationscitations
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article
Formation of porous natural-synthetic polymer composites using emulsion templating and supercritical fluid assisted impregnation
Abstract
Porous natural-synthetic polymer composites were prepared using an alginate emulsion templating step followed by supercritical carbon dioxide (sc-CO 2) assisted impregnation (and subsequent polymerisation) of synthetic monomer mixtures. In the impregnation step, an initiator and either 2-hydroxyethylmethacrylate (HEMA), butylmethacrylate (BMA), ethyleneglycoldimethacrylate (EGDMA) or trimethylolpropanetrimethacrylate (TRIM) monomers, respectively, were used. After impregnation into the porous alginate foam, the synthetic monomer(s) were polymerised in situ, forming porous composites with increased stiffness. A number of methods were used to assess the effects of the impregnation/polymerisation process including uniaxial compression testing, scanning electron microscopy (SEM), mercury intrusion porosimetry (MIP), helium pycnometry and Fourier transform infra-red (FTIR) spectroscopy. Our results suggest that alginate foams impregnated with HEMA show higher weight gains and are stiffer than those impregnated with BMA. Such stiffer porous composites are potentially better suited than the unmodified materials in applications such as tissue engineering (cell-seeded) scaffolds, where mechanical conditioning is desired to stimulate cells for development of neo tissue growth. © Springer-Verlag 2007.